di(phenoxyacetato)phenylantimony(III) | 911823-37-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di(phenoxyacetato)phenylantimony(III)
• 英文别名: [(2-Phenoxyacetyl)oxy-phenylstibanyl] 2-phenoxyacetate
• CAS: 911823-37-5
• 化学式: C₂₂H₁₉O₆Sb
• 分子量: 501.139
• InChiKey: WJCRHRLSZORWTQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.63
• 重原子数：
  29
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  二氯苯基锑 、 sodium phenoxyacetate 在 18crown-6 ether 作用下， 以 苯 为溶剂， 以73%的产率得到di(phenoxyacetato)phenylantimony(III)
  参考文献：
  名称：

  Preparation and Characterization of Arylantimony(III)Aryloxyacetates Ar_nSbL_3−n

  摘要：

  A series of hitherto unreported arylantimony(III)aryloxyacetates of the general formula ArnSbL3-n(n = 1: L = OCOCH2OC6-H-3(CH3)(2)-2,3 (1); OCOCH(CH3)OC6H4(CH3)-p (2); OCOCH2OC6H5 (3); OCOCH2OC10H7-beta (4); OCOCH2OC6H4 (CH3)-p (5); OCOCH2OC6H4 Cl-o (6); OCOCH2OC6H4Cl-p (7); n = 2: L = OCOCH (CH3) OC6H4(CH3)-p (8); OCOCH2OC6H3(CH3)(2)-2,3 (9); OCOCH2OC6H4Cl-o (10); have been prepared by the metathesis of ArnSbCl3-n with aryloxyacetic acids. These have been characterized by elemental analysis, IR, H-1 NMR spectra and UV spectra. Molar conductance and molecular weight data show them to be nonelectrolyte and having covalent monomeric constitution. These complexes were found to possess moderate to significant antifungal and antibacterial activity.

  DOI：

  10.1080/15533170500359562