| 320572-48-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并呋喃类
• CAS: 320572-48-3
• 化学式: C₃₆H₃₂F₆N₂O₇
• 分子量: 718.65
• InChiKey: UCSLKSYXJDSPQW-AVSVCXOUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.53
• 重原子数：
  51.0
• 可旋转键数：
  4.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  86.77
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  dimethyl (1S,12R,13S,14R,16S,17R)-3,10-dimethoxy-15-oxahexacyclo[10.5.1.02,11.04,9.013,17.014,16]octadeca-2,4,6,8,10-pentaene-14,16-dicarboxylate 、 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Photochemical Cycloaddition Reagents for Rigidly Attaching the 1,4-Dimethoxynaphthalene Chromophore to Scaffold Alkenes

  摘要：

  The norbornanecyclobutene epoxides 1a-1c containing a fused 1,4-dimethoxynaphthalene chromophore have been reacted with cyclobutenes, cyclohexenes, norbornenes, 7-isopropylidenenorbornenes, 7-azanorbornenes, and other cyclic or electron-deficient alkenes at room temperature to form 1:1 adducts in stereoselective 1,3-dipolar cycloaddition reactions; alkynes can also participate in this reaction, The ability to form 2:1 adducts has also been demonstrated, thereby opening up opportunities for preparing functionalized products with large chromophore separations.

  DOI：

  10.1021/ol006571d
• 作为产物：
  描述：

  、 dimethyl (1S,12R,13S,14R,16S,17R)-3,10-dimethoxy-15-oxahexacyclo[10.5.1.02,11.04,9.013,17.014,16]octadeca-2,4,6,8,10-pentaene-14,16-dicarboxylate 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Photochemical Cycloaddition Reagents for Rigidly Attaching the 1,4-Dimethoxynaphthalene Chromophore to Scaffold Alkenes

  摘要：

  The norbornanecyclobutene epoxides 1a-1c containing a fused 1,4-dimethoxynaphthalene chromophore have been reacted with cyclobutenes, cyclohexenes, norbornenes, 7-isopropylidenenorbornenes, 7-azanorbornenes, and other cyclic or electron-deficient alkenes at room temperature to form 1:1 adducts in stereoselective 1,3-dipolar cycloaddition reactions; alkynes can also participate in this reaction, The ability to form 2:1 adducts has also been demonstrated, thereby opening up opportunities for preparing functionalized products with large chromophore separations.

  DOI：

  10.1021/ol006571d