zinc;N,N-di(propan-2-yl)carbamodithioate;1,10-phenanthroline | 251569-08-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: zinc;N,N-di(propan-2-yl)carbamodithioate;1,10-phenanthroline
• CAS: 251569-08-1
• 化学式: C₂₆H₃₆N₄S₄Zn
• 分子量: 598.253
• InChiKey: MKYMSRISEGJGNT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.65
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  98.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  二(二丙烷-2-基氨基甲二硫酸)锌 、 邻菲罗啉 以 氯仿 为溶剂， 以75%的产率得到zinc;N,N-di(propan-2-yl)carbamodithioate;1,10-phenanthroline
  参考文献：
  名称：

  Synthesis and crystal structure of ZnPhen(i-Pr2NCS2)2 and molecule packing types in complexes ZnPhen(R2NCS2)2 (R=Me, Et, i-Pr, n-Pr, i-Bu, n-Bu)

  摘要：

  A novel mixed-ligand complex ZnPhen(i-Pr2NCS2)(2) has been synthesized and its single crystals grown. We have determined its crystal structure from X-ray diffraction data. The structure consists of monomeric molecules, a zinc atom surrounded by two nitrogen and four sulfur atoms making a distorted octahedron. Various packing modes of molecules forming isolated 'dimers', ribbons (chains), columns and layers have emerged from the study of the spatial molecule arrangement in the complexes ZnPhen(R2NCS2)(2) (R=Me, Et, i-Pr, n-Pr, i-Bu, n-Bu). The interactions between the Phen molecules have also been studied for these complexes. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00287-9

文献信息

• Larionov; Klevtsova; Shchukin, Russian Journal of Coordination Chemistry, 1999, vol. 25, # 10, p. 694 - 700
  作者：Larionov、Klevtsova、Shchukin、Glinskaya、Zemskova

  DOI：——

  日期：——