| 144718-13-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 144718-13-8
• 化学式: C₁₇H₂₁Cl₂MnN₅
• 分子量: 421.231
• InChiKey: MJQPAQINLRTLQP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Consequences of electronic/steric effects on monochelate and bischelate manganese(II) (S = ) complexes using pyridinylpyrazole ligands. Synthesis and electrochemistry

  摘要：

  A group of three high-spin manganese(II) bis-chelates were synthesized using tridentate 2,6-bis(pyrazol-1-ylmethyl)pyridine and its methyl substituted derivatives. The complexes were isolated as crystalline diperchlorate salts. Two five-coordinate mono-chelates with two chlorides as co-ligands were also synthesized. All the complexes were characterized using conventional physico-chemical techniques. Nucleophilic halide displacement reactions in water on the dichloro complexes afforded aqua complexes. When examined by cyclic voltammetry each complex displays an irreversible Mn(III)/Mn(II) couple. The trends in the anodic peak potentials are rationalized on the basis of electronic/steric effects of the methyl groups present near the donor site.

  DOI：

  10.1016/s0277-5387(00)83160-5