bis(diisopropylselenophosphoryl)ferrocene dihydrate | 354807-46-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: bis(diisopropylselenophosphoryl)ferrocene dihydrate
• 英文别名: dippfSe2；cyclopenta-2,4-dien-1-yl-di(propan-2-yl)-selanylidene-λ5-phosphane;iron(2+)
• CAS: 354807-46-8
• 化学式: C₂₂H₃₆FeP₂Se₂
• 分子量: 576.242
• InChiKey: UAKZKTQWNLDVNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  selenium 、 二茂铁 、 氯二异丙基膦 在 n-butyllithium 、 N,N,N',N'-tetramethylethylenediamine 作用下， 以 氯仿 为溶剂， 以25.1%的产率得到bis(diisopropylselenophosphoryl)ferrocene dihydrate
  参考文献：
  名称：

  The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(η5-C5H4)P(O) Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(η5-C5H4)P(S) Pr2]2, and bis(diisopropylselenophosphoryl)ferrocene Fe[(η5-C5H4)P(Se) Pr2]2, the oxidised derivatives of bis(diisopropylphosphino)ferrocene

  摘要：

  The synthesis and spectroscopic characterisation of three chalcogenophosphoryl ligands derived from ferrocene is reported. The synthesis was based on the oxidation of Fe[(eta (5)-C5H4)P ' Pr-2](2) by elementary sulfur and selenium, and hydrogen peroxide, respectively. All new compounds were characterised by X-ray crystallography and comparison with their aryl analogues was made. Contrary to Fe[(eta (5)-C5H4)P(E)Ph-2](2) (E = O, S, Se), the prepared compounds are not centrosymmetric, with the iso-propyl groups showing more flexibility than the phenyl substituents. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00709-4