(9Z)-9,13-tetradecadien-11-yn-1-yl acetate | 1048005-51-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (9Z)-9,13-tetradecadien-11-yn-1-yl acetate
• 英文别名: [(9Z)-tetradeca-9,13-dien-11-ynyl] acetate
• CAS: 1048005-51-1
• 化学式: C₁₆H₂₄O₂
• 分子量: 248.365
• InChiKey: VFGYPJTWYVBPAS-SREVYHEPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (9Z)-9,13-tetradecadien-11-yn-1-ol 、 乙酸酐 在 吡啶 作用下， 以80%的产率得到(9Z)-9,13-tetradecadien-11-yn-1-yl acetate
  参考文献：
  名称：

  (9Z)-9,13-Tetradecadien-11-ynal, the sex pheromone of the avocado seed moth, Stenoma catenifer

  摘要：

  The highly unsaturated aldehyde (9Z)-9,13-tetradecadien-11-ynal and the corresponding alcohol were identified as possible sex pheromone components of the avocado seed moth, Stenoma catenifer. The aldehyde as a single component attracted more male moths than caged virgin female moths, and addition of the analogous alcohol and/or acetate decreased attraction. A stereospecific synthesis of the pheromone is described. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.06.019