[η(5)-C5H5)Fe(CO)2]C3N2O3 | 716327-47-8

• 英文名称: [η(5)-C5H5)Fe(CO)2]C3N2O3
• CAS: 716327-47-8
• 化学式: C₁₇H₁₀Fe₂N₂O₇
• 分子量: 465.97
• InChiKey: XKXIOOOWMPEPJM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  仲班酸 、 [η(5)-C5H5)Fe(CO)2]C3N2O3 在 iPr₂NH 作用下， 以 not given 为溶剂， 生成 (η(5)-C5H5)Fe(CO)2(C3N2HO3)
  参考文献：
  名称：

  [(η5-C5H5)Fe(CO)2](Fp)-complexes of the parabanic acid mono- and dianion: synthesis, X-ray structures and reactivity of the heterocyclic ligand

  摘要：

  [(eta(5)-C5H5)Fe(CO)(2)](Fp)-complexes of the parabanic acid mono- and dianion have been synthesised in a photochemical reaction of FpI with parabanic acid and diisopropylamine in benzene. The former contains a reactive N(3)-H bond and can be readily thallated with TlOEt. Reaction of the thallated complex with Ph3PAuCl, benzyl chloride and ethyl bromoacetate in DMF gave N(3)-aurated, N(3)-benzyl and N(3)-carboethoxymethyl complex, respectively. The structures of these complexes were confirmed by X-ray diffraction. The ester function in the N(3)-carboethoxymethyl complex was hydrolysed to afford air-stable, water-soluble acid, a potential metallocarbonyl labelling reagents for proteins. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.02.015
• 作为产物：
  描述：

  仲班酸 、 dicarbonylcyclopentadienyliodoiron(II) 在 iPr₂NH 作用下， 以 苯 为溶剂， 以40%的产率得到(η(5)-C5H5)Fe(CO)2(C3N2HO3)
  参考文献：
  名称：

  [(η5-C5H5)Fe(CO)2](Fp)-complexes of the parabanic acid mono- and dianion: synthesis, X-ray structures and reactivity of the heterocyclic ligand

  摘要：

  [(eta(5)-C5H5)Fe(CO)(2)](Fp)-complexes of the parabanic acid mono- and dianion have been synthesised in a photochemical reaction of FpI with parabanic acid and diisopropylamine in benzene. The former contains a reactive N(3)-H bond and can be readily thallated with TlOEt. Reaction of the thallated complex with Ph3PAuCl, benzyl chloride and ethyl bromoacetate in DMF gave N(3)-aurated, N(3)-benzyl and N(3)-carboethoxymethyl complex, respectively. The structures of these complexes were confirmed by X-ray diffraction. The ester function in the N(3)-carboethoxymethyl complex was hydrolysed to afford air-stable, water-soluble acid, a potential metallocarbonyl labelling reagents for proteins. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.02.015