Mn(adipate)(trans-1,2-bis(4-pyridyl)ethene) | 494754-27-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Mn(adipate)(trans-1,2-bis(4-pyridyl)ethene)
• 英文别名: hexanedioate;manganese(2+);4-[(E)-2-pyridin-4-ylethenyl]pyridine
• CAS: 494754-27-7
• 化学式: C₆H₈O₄*C₁₂H₁₀N₂*Mn
• 分子量: 381.29
• InChiKey: XQMXORFSKYOJJI-SEPHDYHBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.69
• 重原子数：
  25.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  Mn(adipate)(trans-1,2-bis(4-pyridyl)ethene) 以 neat (no solvent) 为溶剂， 生成 manganese(III) oxide
  参考文献：
  名称：

  Synthesis and characterization of coordination polymers with interpenetrated frameworks: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn

  摘要：

  Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M = Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of CO2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N'-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00905-2
• 作为产物：
  描述：

  己二酸 、 manganese(II) chloride tetrahydrate 、 1,2-二(4-吡啶基)乙烯 以 乙醇 、 水 为溶剂， 以50.1%的产率得到Mn(adipate)(trans-1,2-bis(4-pyridyl)ethene)
  参考文献：
  名称：

  Synthesis and characterization of coordination polymers with interpenetrated frameworks: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn

  摘要：

  Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M = Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of CO2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N'-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00905-2