{Cd(II)(pyrroporphyrin)} | 156791-19-4

• 分子结构分类: 有机化合物
• 英文名称: {Cd(II)(pyrroporphyrin)}
• CAS: 156791-19-4
• 化学式: C₃₂H₃₄CdN₄O₂
• 分子量: 619.058
• InChiKey: BAJPIQXMHYZCCF-GOSCMBTDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Cd(II)(pyrroporphyrin)} 、 zinc(II) chloride 以 二甲基亚砜 为溶剂， 生成 {Zn(II)(pyrroporphyrin)}
  参考文献：
  名称：

  Double metal-ligand exchange in solvate complex-metal porphyrin systems

  摘要：

  The kinetics and mechanism of one of the most complicated chemical reactions of coordination compounds, where two different porphyrin complexes exchange central metal ions and the corresponding ligands, were considered using a number of metal porphyrins as substrates.

  DOI：

  10.1134/s1070363213070189
• 作为产物：
  描述：

  pyrroporphyrin 、 cadmium(II) nitrate 以 乙酸乙酯 为溶剂， 生成 {Cd(II)(pyrroporphyrin)}
  参考文献：
  名称：

  Berezin, B. D.; Daniyarov, D. D.; Askarov, K. A., Russian Journal of Physical Chemistry, 1992, vol. 66, # 6, p. 867 - 870

  摘要：

  DOI：

文献信息

• Berezin, M. B.; Daniyarov, D. D.; Berezin, B. D., Russian Journal of Inorganic Chemistry, 1991, vol. 36, p. 980 - 982
  作者：Berezin, M. B.、Daniyarov, D. D.、Berezin, B. D.、Askarov, K. A.

  DOI：——

  日期：——
• Kinetics of the metal-ligand exchange of cadmium rhodo- and pyrroporphyrins with cobalt and zinc chlorides in organic solvents
  作者：B. D. Berezin、S. V. Zvezdina、M. B. Berezin

  DOI：10.1134/s0036023613060065

  日期：2013.6

  Experimental data on electron absorption spectra (EASs) and the kinetics of substitution of Co2+ for the central Cd2+ ion in rhodoporphyrin complexes (CdRodP) in the reaction with CoCl2 in acetonitrile (AN) and ZnCl2 in dimethyl sulfoxide (DMSO) and the substitution of Zn2+ for Cd2+ in pyrroporphyrin complexes (CdPyrP) in the reaction with ZnCl2 in DMSO are reported and discussed. The evolution of EASs in the reaction of metal-ligand exchange and the effective and true rate constants of the exchange reaction are reported. The activation energies and activation entropies are estimated.