5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene) | 1106732-15-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)
• 英文别名: 5,17-bis-(zinc meso-phenylporphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix[4]arene
• CAS: 1106732-15-3
• 化学式: C₁₀₆H₁₀₄N₈O₄Zn₂
• 分子量: 1684.82
• InChiKey: XVUAPLPXNJAFGA-FCMUQYKXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene) 、 1,3-丙二胺 以 甲苯 为溶剂， 生成 5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)-bis(1,3-diaminopropane)
  参考文献：
  名称：

  The effect of the structure of aliphatic diamines on their interaction with zinc porphyrinates

  摘要：

  The complex formation of zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethylporphyrinate, 5,17-bis(zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylporphyrinate)-25,27-dimethoxy-26,28-dihydroxycalic-[4]-arene, and 5,17-bis(zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylporphyrinate)-25,27-dimethoxy-26,28-crwon-[6]-calix-[4]-arene with 1,2-diaminoethane, 1,3-diaminopropane, and 1,2-di-(dimethylamino)ethane in toluene was studied by spectrophotometric molar ratio method and H-1 NMR. The effect of the diamine structure on the formation of "internal" and "external" porphyrinate-ligand complexes of the composition 1 :1 and 1 :2 was established. The stability constants of the complexes obtained were calculated and the concentration intervals of their formation were determined.

  DOI：

  10.1134/s1070328408060067
• 作为产物：
  描述：

  bis(3-ethyl-4-methyl-1H-pyrrol-2-yl)methane 、 zinc diacetate 、 26,28-Dihydroxy-25,27-dimethoxypentacyclo<19.3.1.1^3,7.1^9,13.1^15,19>octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-5,17-dicarboxaldehyde 、 苯甲醛 在 三氯乙酸 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 以6%的产率得到5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)
  参考文献：
  名称：

  Calix[4]arene-porphyrin molecular receptors for selective binding of ethylenediamines

  摘要：

  A new zinc calix[4]arene-bis-porphyrinate was synthesized and its 1 : 1 and 1 : 2 complexation reaction with ehtylenediamine, diethylenediamine, and triethylenediamine in toluene at 298 K was studied by spectrophotometric titration and H-1 NMR.

  DOI：

  10.1134/s1070328407100119