1,1'-thio-bis-(2-naphthoxy-(methyl acetate)) | 930598-36-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1'-thio-bis-(2-naphthoxy-(methyl acetate))
• 英文别名: 1,1'-thiobis-(2-naphthoxy(2-methyl acetate))；1,1'-thiobis(2-naphthoxyhydrazide)
• CAS: 930598-36-0
• 化学式: C₂₆H₂₂O₆S
• 分子量: 462.523
• InChiKey: JDPZSUWUQDDOPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.25
• 重原子数：
  33.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  71.06
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  1,1'-thio-bis-(2-naphthoxy-(methyl acetate)) 在 一水合肼 作用下， 以 甲醇 为溶剂， 反应 20.0h， 以85%的产率得到1,1'-thiobis(2-naphthoxyhydrazide)
  参考文献：
  名称：

  Novel polyoxadiazoles with non-coplanar ortho-linked structures as highly CO₂ permselective membranes

  摘要：

  一种新型聚氧二嗪膜类别，包含非共面的1,1'-硫醚基(2-萘氧)基团，使用多功能路线合成并用于CO2分离测试。在氧化后，含磺酰基的膜表现出更高的渗透性和更低的选择性。

  DOI：

  10.1039/c4ra01595a
• 作为产物：
  描述：

  1,1'-硫联二(2-萘酚) 、 氯乙酸甲酯 在 potassium carbonate 、 potassium iodide 作用下， 以 乙腈 为溶剂， 以91%的产率得到1,1'-thio-bis-(2-naphthoxy-(methyl acetate))
  参考文献：
  名称：

  BINOL Aza Macrocycle Derivatives: Synthesis of Dinaphthosulfone Aza Macrocycles Using p-Toluenesulfonic Acid (p-TsOH) in Methanol as an Efficient Route and Evaluation of Their ¹H NMR Spectra

  摘要：

  Dinaphthosulfone aza macrocycles were synthesized from the reaction of diamines and dinaphthosulfone diester (1,1'-sulfoxobis-(2-naphthoxy(2-methyl acetate))) in methanol in the presence of catalytic amounts of para toluenesulfonic acid (p-TsOH). Dinaphthosulfone diester (1,1'-sulfoxobis-(2-naphthoxy(2-methyl acetate))) was synthesized from the corresponding dinaphthosulfide diester and hydrogen peroxide in formic acid at room temperature. Dinaphthosulfide diester was prepared from initial dinaphtholsulfide diol (1,1'-thio bis(2-hydroxy naphthalene)) and methylchloroacetate. H-1 NMR spectroscopy showed the unusual splittings for these dinaphthosulfone aza macrocycles, and this finding could be proposed as the role of tetrahedral structure of sulfone functional group, hydrogen bonding in the cavity and size of macrocycle.

  DOI：

  10.1080/10426500802421036

文献信息

• Efficient Route for the Synthesis of New Dinaphthosulfoxide Aza Crowns Using Ethyleneglycol Under Microwave (MW) Irradiation: Macrocyclization is Preferred to Oligomerization Under MW Irradiation
  作者：Esmael Rostami

  DOI：10.1080/10426507.2010.544270

  日期：2011.9.1
• Efficient Routes for the Synthesis of Dinaphthosulfide (BINOL Derivatives) and Dibenzosulfide Aza Podands Containing Ethanolamine
  作者：Esmael Rostami、Davood Heidaryan、Hanif Fattahi、Abbas Shockravi、Mehdi Zarei、Farokh Rakhshanderu

  DOI：10.1080/10426500802417059

  日期：2009.7.13

  Four new dinaphthosulfide and dibenzosulfide aza podands were synthesized. The synthesis of these podands was performed under three different reaction conditions: 1) diester, K(2)CO(3), methanol, and RT; 2) diester, ethanolamine, and microwave (MW); and 3) diacid dichloride, ethanolamine, Et(3)N, CH(2)Cl(2), RT. Two kinds of diester (dinaphthosulfide and dibenzosulfide) were used for the preparation of dihydroxy podands. These dihydroxy podands were reacted with thionyl chloride to afford dichloro podands. The second route gave excellent yields of dihydroxy podands. Dichloro podands are more soluble than dihydroxy podands in conventional solvents such as methanol, chloroform, and acetonitrile.
• Rostami; Zare, E-Journal of Chemistry, 2011, vol. 8, # SUPPL. 1, p. S7-S12
  作者：Rostami、Zare

  DOI：——

  日期：——