1,10-Di-imidazol-1-yl-decane-1,10-dione | 26506-46-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,10-Di-imidazol-1-yl-decane-1,10-dione
• 英文别名: 1,10-Di(imidazol-1-yl)decane-1,10-dione
• CAS: 26506-46-7
• 化学式: C₁₆H₂₂N₄O₂
• 分子量: 302.376
• InChiKey: DQQZYLLZHJYUDF-UHFFFAOYSA-N

物化性质

• 沸点：
  505.7±60.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  69.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,10-Di-imidazol-1-yl-decane-1,10-dione 在 羟胺 作用下， 以 甲醇 为溶剂， 反应 0.5h， 生成 癸烷-1,8-二氧肟酸
  参考文献：
  名称：

  Conformational behaviour of hydroxamic acids: ab initio and structural studies

  摘要：

  The conformational behaviour of a series of monohydroxamic acids, p-RC(6)H(4)CONR'OH (R = Me, R' = H, Me; R = MeO, R' = H, Me; R = NO2, R' = H), and a series of dihydroxamic acids, (CH2)(n)(CONR'OH)(2) (n = 3-8, 10, R' = H and n = 7, R' = Me), in methanol, DMSO and chloroform and in the solid state has been examined using IR and NMR spectroscopy, X-Ray crystal structure determinations of p-MeC(6)H(4)CONMeOH and the monohydrate of glutarodihydroxamic acid (n = 3) together with ab initio molecular orbital calculations for several hydrated and unhydrated hydroxamic acids have been performed. Hydrogen bonding effects are shown to be important in both the solid state and solution, The cis(Z) conformation of the hydroxamate group(s) (CONHOH) is preferentially stabilized by hydrogen bonding with water molecules.

  DOI：

  10.1039/p29960002673
• 作为产物：
  描述：

  癸二酸 、 N,N'-羰基二咪唑 以 四氢呋喃 为溶剂， 反应 24.0h， 生成 1,10-Di-imidazol-1-yl-decane-1,10-dione
  参考文献：
  名称：

  Brown, D. A.; Geraty, R. A.; Glennon, J. D., Synthetic Communications, 1985, vol. 15, # 13, p. 1159 - 1164

  摘要：

  DOI：

文献信息

• Cured film and method for producing same
  申请人：TORAY INDUSTRIES, INC.

  公开号：US10908500B2

  公开（公告）日：2021-02-02

  Provided is a cured film having high chemical resistance, high elongation, and high adhesion to metal copper. A cured film formed by curing a photosensitive resin composition containing a polybenzoxazole precursor, in which a rate at which the polybenzoxazole precursor is cyclized into polybenzoxazole is not less than 10% and not more than 60%.

  本发明提供了一种具有高耐化学腐蚀性、高伸长率以及与金属铜的高粘合性的固化膜。通过固化含有聚苯并恶唑前体的光敏树脂组合物而形成的固化膜，其中聚苯并恶唑前体环化成聚苯并恶唑的速率不低于 10%，不高于 60%。
• Interstrand DNA cross-linking with dimers of the spirocyclopropyl alkylating moiety of CC-1065
  作者：Mark A. Mitchell、Paul D. Johnson、Marta G. Williams、Paul A. Aristoff

  DOI：10.1021/ja00198a068

  日期：1989.8
• MITCHELL, MARK A.;JOHNSON, PAUL D.;WILLIAMS, MARTA G.;ARISTOFF, PAUL A., J. AMER. CHEM. SOC., 111,(1989) N6, C. 6428-6429
  作者：MITCHELL, MARK A.、JOHNSON, PAUL D.、WILLIAMS, MARTA G.、ARISTOFF, PAUL A.

  DOI：——

  日期：——
• CURED FILM AND METHOD FOR PRODUCING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20190004423A1

  公开（公告）日：2019-01-03

  Provided is a cured film having high chemical resistance, high elongation, and high adhesion to metal copper. A cured film formed by curing a photosensitive resin composition containing a polybenzoxazole precursor, in which a rate at which the polybenzoxazole precursor is cyclized into polybenzoxazole is not less than 10% and not more than 60%.