申请人:KURARAY CO., LTD.
公开号:EP0774477A2
公开(公告)日:1997-05-21
Copolyesters consisting essentially of terephthalic acid units and ethylene glycol units, and further comprising 1 to 4 mole % of alicyclic or aliphatic bifunctional compound units (a1) or 0.5 to 7 mole % of bifunctional compound units (a2) derived from a specific aromatic diol or bifunctional compound units (a3) derived from a condensed ring or ring assembly type aromatic dicarboxylic acid, 0.005 to 1 mole % of multi-functional compound units (b1), and a specific amount of monofunctional compound units (c); copolyesters having a specific intrinsic viscosity and consisting essentially of terephthalic acid units and ethylene glycol units, and further comprising 0.5 to 7 mole % of the above bifunctional compound units (a2) and 0.005 to 1 mole % of specific multi-functional compound units (b2) or (b3); and
copolyesters consisting essentially of terephthalic acid units and ethylene glycol units, and further comprising 0.5 to 7 mole % of the above bifunctional compound units (a3) and 0.005 to 0.5 mole % of the multi-functional compound units (b1).
These copolyesters have excellent melt moldability, in particular extrusion blow moldability and give molded articles having excellent transparency, impact resistance, gelation characteristics, appearance, tactility, mechanical properties, heat resistance, chemical resistance and dimensional precision.
主要由对苯二甲酸单元和乙二醇单元组成的共聚物,并进一步包含 1 至 4 摩尔%的脂环族或脂肪族双官能化合物单元(a1)或 0.5 至 7 摩尔%的衍生自特定芳香族二元醇的双官能化合物单元(a2)或衍生自缩合环或环组装型芳香族二羧酸的双官能化合物单元(a3)、0.005至1摩尔%的多功能化合物单元(b1),以及特定量的单官能化合物单元(c);具有特定固有粘度且主要由对苯二甲酸单元和乙二醇单元组成的共聚物,进一步包含0.5至7摩尔%的上述双官能化合物单元(a2)和0.005至1摩尔%的特定多功能化合物单元(b2)或(b3);以及
主要由对苯二甲酸单元和乙二醇单元组成的共聚物,还包括 0.5 至 7 摩尔%的上述双官能化合物单元(a3)和 0.005 至 0.5 摩尔%的多功能化合物单元(b1)。
这些共聚多酯具有极佳的熔融模塑性,尤其是挤出吹塑成型性,可制成具有极佳透明度、抗冲击性、凝胶化特性、外观、触感、机械性能、耐热性、耐化学性和尺寸精度的成型制品。