2,2',4,4',6,6'-hexafluoro-3,3',5,5'-tetraiodobiphenyl | 872010-03-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2',4,4',6,6'-hexafluoro-3,3',5,5'-tetraiodobiphenyl
• 英文别名: 1,3,5-Trifluoro-2,4-diiodo-6-(2,4,6-trifluoro-3,5-diiodophenyl)benzene
• CAS: 872010-03-2
• 化学式: C₁₂F₆I₄
• 分子量: 765.74
• InChiKey: JCQRSJZUJOJFBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,2',4,4',6,6'-hexafluoro-3,3',5,5'-tetraiodobiphenyl 在 copper(l) iodide 、 四(三苯基膦)钯 、 四丁基氟化铵 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 3,3',5,5'-tetraethynyl-2,2',4,4',6,6'-hexafluorobiphenyl
  参考文献：
  名称：

  Rational Design and Synthesis of Porous Polymer Networks: Toward High Surface Area

  摘要：

  Head-on polymerization of tetrahedral monomers inherently imparts interconnected diamond cages to the resulting framework with each strut widely exposed. We have designed and synthesized a series of 3,3',5,5'-tetraethynylbiphenyl monomers, in which the two phenyl rings are progressively locked into a nearly perpendicular position by adding substituents of different size at 2, 2', 6, and 6' positions, as evident from single crystal structures. Computational simulation suggests that these monomers, though not perfectly regular tetrahedra, could still be self-polymerized into three-dimensional frameworks with the same topology. Indeed, five porous polymer networks (PPNs) have been successfully synthesized with these newly designed monomers through Cu(II)-promoted Eglinton homocoupling reaction. Among them, PPN-13 shows exceptionally high Brunauer-Emmett-Teller (BET) surface area of 3420 m(2)/g. The total hydrogen uptake is 52 mg/g at 40 bar and 77 K, and the total methane uptake is 179 mg/g at 65 bar and 298 K.

  DOI：

  10.1021/cm501922h
• 作为产物：
  描述：

  1,3,5-三氟-2-(2,4,6-三氟苯基)苯 在 sodium periodate 、 硫酸 、 potassium iodide 作用下， 生成 2,2',4,4',6,6'-hexafluoro-3,3',5,5'-tetraiodobiphenyl
  参考文献：
  名称：

  [EN] SINGLE CRYSTAL, MATERIAL FOR NANOWIRING, ELECTRONIC DEVICE, AND PROCESS FOR PRODUCING MATERIAL FOR NANOWIRING
  [FR] NANOFIL MONOCRISTALLIN, DISPOSITIF ÉLECTRONIQUE, ET PROCESSUS DE PRODUCTION DE NANOFIL

  摘要：

  可以提供用于纳米级线路的纳米线材料。采用了具有高电阻率各向异性的分子单晶。

  公开号：

  WO2005123637A1

文献信息

• Monocrystal, Nano Wire Material, Electronic Element, and Method of Producing Nano Wire Material
  申请人：Yamamoto Hiroshi

  公开号：US20080124545A1

  公开（公告）日：2008-05-29

  A crystalline nano wire material which can be used as a nano-level wire is provided. A molecular monocrystal having a high anisotropy for electrical resistivity is used.
• US7771820B2
  申请人：——

  公开号：US7771820B2

  公开（公告）日：2010-08-10