1,3-bis[bis(trimethylsilyl)methyldichlorostannyl]propane | 212476-54-5

• 分子结构分类: 有机化合物
• 英文名称: 1,3-bis[bis(trimethylsilyl)methyldichlorostannyl]propane
• 英文别名: 1,3-Bis[bis(trimethylsilyl)methyl-dichloro-stannyl]propane；[[3-[bis(trimethylsilyl)methyl-dichlorostannyl]propyl-dichlorostannyl]-trimethylsilylmethyl]-trimethylsilane
• CAS: 212476-54-5
• 化学式: C₁₇H₄₄Cl₄Si₄Sn₂
• 分子量: 740.11
• InChiKey: INULIAYLYZUHCL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  9.47
• 重原子数：
  27
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3-bis[bis(trimethylsilyl)methyldichlorostannyl]propane 在 (t-Bu₂SnO)3 作用下， 以 氘代氯仿 为溶剂， 生成 1,3,7,9-tetrakis[bis(trimethylsilyl)methyl]-2,8,13,14-tetraoxa-tricyclo[7.3.1.1(3,7)]-1,3,7,9-tetrastannatetradecane
  参考文献：
  名称：

  Novel Molecular Organotin Oxides Derived from Alkylidene Bridged Ditin Precursors:  Syntheses and Structures^,

  摘要：

  New diorganotin compounds (RCl2Sn)(2)(CR'(2))(n) [R = (SiMe3)(2)CH; R' = Me, H; n = 1-3] Linked by various spacers have been synthesized. These react with sodium hydroxide or (t-Bu2SnO)(3) to give (R(O)Sn)(2)(CR'(2))(n). Compounds 8 (R' = Me, n = 1), 9 (R' = H, n = 2), and 10 (R' = H, n = 3) contain four-coordinate tin atoms. Compound 9 undergoes a reversible hydrolysis reaction from which a solid containing three ditin units has been isolated. Evidence is presented for the existence in solution of monomeric four-coordinate tin compounds (RXSn)(2)(CH2)(3)O [R = (SiMe3)(2)CH, X = Cl, OH]. Crystal structures for monomeric ditin precursors 2,2-bis[bis(trimethylsilyl)methyldichlorostannyl]propane (3) and 1,2-bis[bis(trimethylsilyl)methyldichlorostannyl]ethane (6), for dimeric units 1,3,5,7-tetrakis[bis(trimethylsilyl)methyl]-9,9,10,10-tetramethyl-2,4,6,8-tetraoxa-1,3,5,7-tetrastannaadamantane (8), 1,3,7,9-tetrakis[bis(trimethylsilyl)methyl]-2,8,13,14-tetraoxatricyclo[7.3.1.13.7]-1,3,7,9-tetrastannatetradecane (10), and 2,6-difluoro-2,6-bis[bis(trimethylsilyl)methyl]-1-oxa-2,6-distannacyclohexane dimer (12), and for trimeric units {O[(RSn(CH2)(2)SnR)OH]OH}(3). 2H(2)O (9a) are reported.

  DOI：

  10.1021/om980369l
• 作为产物：
  描述：

  bis(trimethylsilyl)methyllithium 以 丙酮 、 正戊烷 为溶剂， 生成 1,3-bis[bis(trimethylsilyl)methyldichlorostannyl]propane
  参考文献：
  名称：

  Novel Molecular Organotin Oxides Derived from Alkylidene Bridged Ditin Precursors:  Syntheses and Structures^,

  摘要：

  New diorganotin compounds (RCl2Sn)(2)(CR'(2))(n) [R = (SiMe3)(2)CH; R' = Me, H; n = 1-3] Linked by various spacers have been synthesized. These react with sodium hydroxide or (t-Bu2SnO)(3) to give (R(O)Sn)(2)(CR'(2))(n). Compounds 8 (R' = Me, n = 1), 9 (R' = H, n = 2), and 10 (R' = H, n = 3) contain four-coordinate tin atoms. Compound 9 undergoes a reversible hydrolysis reaction from which a solid containing three ditin units has been isolated. Evidence is presented for the existence in solution of monomeric four-coordinate tin compounds (RXSn)(2)(CH2)(3)O [R = (SiMe3)(2)CH, X = Cl, OH]. Crystal structures for monomeric ditin precursors 2,2-bis[bis(trimethylsilyl)methyldichlorostannyl]propane (3) and 1,2-bis[bis(trimethylsilyl)methyldichlorostannyl]ethane (6), for dimeric units 1,3,5,7-tetrakis[bis(trimethylsilyl)methyl]-9,9,10,10-tetramethyl-2,4,6,8-tetraoxa-1,3,5,7-tetrastannaadamantane (8), 1,3,7,9-tetrakis[bis(trimethylsilyl)methyl]-2,8,13,14-tetraoxatricyclo[7.3.1.13.7]-1,3,7,9-tetrastannatetradecane (10), and 2,6-difluoro-2,6-bis[bis(trimethylsilyl)methyl]-1-oxa-2,6-distannacyclohexane dimer (12), and for trimeric units {O[(RSn(CH2)(2)SnR)OH]OH}(3). 2H(2)O (9a) are reported.

  DOI：

  10.1021/om980369l