diaqua-bis[2-(methoxyimino)-propanato]-zinc(II) | 835873-91-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diaqua-bis[2-(methoxyimino)-propanato]-zinc(II)
• 英文别名: di-auqo-bis[2-(methoxyimino)propanoato]zinc(II)；di-aqua-bis[2-(methoxyimino)propanoato]zinc
• CAS: 835873-91-1
• 化学式: C₈H₁₆N₂O₈Zn
• 分子量: 333.614
• InChiKey: CZAJGATWNJVIQS-FSOOZVBNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  diaqua-bis[2-(methoxyimino)-propanato]-zinc(II) 以 further solvent(s) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  溶液处理的 ZnO - 柔性基板上的加工和性能挑战

  摘要：

  半导体ZnO薄膜是通过在中等温度下将复杂的二水-双[2-(甲氧基亚氨基)-丙酸根]-锌(II)热分解成纳米级ZnO而获得的。这种单一来源的前体适用于在聚合物基材上旋涂和喷墨印刷，例如聚对苯二甲酸乙二醇酯 (PET) 和聚萘二甲酸乙二醇酯 (PEN) 透明胶片，在这些基材上已进行了氧化锌的转化。研究了不同干燥程序和转化温度对活性半导体材料ZnO的影响，对薄膜形貌和场效应晶体管的电子性能的影响。

  DOI：

  10.1002/pssa.200983749
• 作为产物：
  描述：

  甲氧基胺盐酸盐 、 水 、 sodium pyruvate 、 zinc(II) nitrate hexahydrate 在 sodium bicarbonate 作用下， 以 水 为溶剂， 以65%的产率得到diaqua-bis[2-(methoxyimino)-propanato]-zinc(II)
  参考文献：
  名称：

  Towards new precursors for ZnO thin films by single source CVD: the X-ray structures and precursor properties of zinc ketoacidoximates

  摘要：

  Zinc complexes of pyruvic and glyoxylic acid oximes have been investigated as potential precursors for single source chemical vapour deposition (SSCVD) of ZnO thin films. The X-ray crystal structures of the complexes and of their NOW analogues reveal markedly different coordination and intermolecular bonding patterns. These structural differences, in conjunction with ligand substituent changes impart different responses to thermogravimetric analysis (TGA), and sublimation. The glyoxylic acid methyloxime Zn(O2CCHN(OMe))(2) . 2H(2)O has volatility and thermolysis properties suitable for SSCVD of ZnO. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.022

文献信息

• A Photochemically Induced Molecular Pathway to Smooth and Transparent Gallium-Doped Zinc Oxide Ceramic
  作者：Rudolf C. Hoffmann、Jörg J. Schneider

  DOI：10.1111/j.1551-2916.2010.04310.x

  日期：2011.6

  The photochemical conversion of the zinc oximato complex of di-aqua-bis[2-(methoxyimino)propanoato]zinc 1 into zinc oxide thin films is introduced as an alternative route compared with the traditional thermal process. Irradiation of 1 by UV light produces smoother films with random orientation of crystalline grains, compared with the thermal route, which results in films with a high degree of (002) orientation (texture) toward the substrate. By addition of Ga(NO3)(3), gallium-doped zinc oxide (GZO) thin films can be obtained after further sintering, e.g., in air. The GZO films exhibit a low surface roughness and a high optical transparency. Electrical resistivities as low as 7.4 x 10-2 center dot cm were observed, making it a candidate for application in the field of transparent conduction oxides.