cadmium cupferronate | 7215-35-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cadmium cupferronate
• 英文别名: N-nitroso-N-phenyl-hydroxylamine; cadmium (II)-compound；[(N-nitroso-N-phenylhydroxylaminate)2 cadmium]；cadmium cupferrate；Cd(cup)2；N-Nitroso-N-phenyl-hydroxylamin; Cadmium(II)-Verbindung
• CAS: 7215-35-2
• 化学式: 2C₆H₅N₂O₂*Cd
• 分子量: 386.646
• InChiKey: DDRXHUDNOBGFJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.67
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.73
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  cadmium cupferronate 以 乙醇 、 乙二胺 为溶剂， 生成 cadmium(II) oxide
  参考文献：
  名称：

  Solvothermal synthesis of nanorods of ZnO, N-doped ZnO and CdO

  摘要：

  ZnO nanorods with diameters in the 80-800 nm range are readily synthesized by the reaction of zinc acetate, ethanol and ethylenediamine under solvothermal conditions. The best products are obtained at 330 degrees C with a slow heating rate. Addition of the surfactant Triton((R))-X 100 gave nanorods of uniform (300 nm) diameter. By adding a small amount of liquid NH3 to the reaction mixture, N-doped ZnO nanorods, with distinct spectroscopic features are obtained. CdO nanorods of 80 nm diameter have been prepared under solvothermal conditions using a mixture of cadmium cupferronate, ethylenediamine and ethanol at 330 degrees C. Similarly, Zn1-xCdxO nanorods of a 70 nm diameter are obtained under solvothermal conditions starting with a mixture of zinc acetate, cadmium cupferronate, ethanol and ethylenediamine. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2007.01.017
• 作为产物：
  描述：

  cupferron 、 cadmium(II) acetate 以 水 为溶剂， 生成 cadmium cupferronate
  参考文献：
  名称：

  A strategy for the synthesis of nanocrystal films of metal chalcogenides and oxides by employing the liquid–liquid interface

  摘要：

  The interface between water and an organic liquid has been exploited to prepare nanocrystals of US. The technique involves introducing an appropriate precursor of cadmium in the organic layer and the sulfiding reagent in the aqueous layer. The size distribution of the nanocrystals formed at the interface can be controlled by varying parameters such as the reactant concentration, temperature, viscosity of the medium, reaction time and the choice of the reagents. The US nanocrystals have been characterized by TEM, electronic absorption and emission spectroscopy. Nanocrystaline gamma-FeO3 and ZnO can be prepared by taking cupferron complex of the metals in the organic layer and NaOH in the aqueous layer. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2003.08.125

文献信息

• Deposition of hierarchical Cd(OH)2 anisotropic nanostructures at the water–toluene interface and their use as sacrificial templates for CdO or CdS nanostructures
  作者：Sibusiso N. Mlondo、Ellen M. Andrews、P. John Thomas、Paul O’Brien

  DOI：10.1039/b806409a

  日期：——

  Hierarchical anisotropic structures ranging from triangular ‘platelets’ to nanofibres of Cd(OH)2 are synthesized at a water–toluene interface; the nanowires are used as sacrificial templates to produce CdO wires and CdS nanostructures, preserving many structural aspects.

  在水和甲苯界面上合成了从三角形 "小板 "到纳米纤维的 Cd(OH)2 各向异性分层结构；纳米线被用作生产 CdO 线和 CdS 纳米结构的牺牲模板，保留了许多结构方面。
• Solvothermal synthesis of CdO and CuO nanocrystals
  作者：Moumita Ghosh、C.N.R. Rao

  DOI：10.1016/j.cplett.2004.06.092

  日期：2004.8

  Nanocrystals of CdO have been obtained by the decomposition of the cupferron complex in the presence of tri-n-octylphosphine oxide (TOPO) under solvothermal conditions. The precursor:TOPO ratio plays an important role in determining the size of the nanocrystals. The nanocrystals have been characterized by electron microscopy, absorption spectroscopy and fluorescence spectroscopy, besides X-ray diffraction. The CdO nanocrystals are single crystalline and show evidence for quantum confinement. CuO nanocrystals could also be prepared by the decomposition of the cupferronate under solvothermal conditions, the particle size being controlled by the initial precursor concentration. (C) 2004 Elsevier B.V. All rights reserved.
• Optical Properties of ZnO Nanocrystals Doped with Cd, Mg, Mn, and Fe Ions
  作者：Y. S. Wang、P. John Thomas、P. O'Brien

  DOI：10.1021/jp0654415

  日期：2006.11.1

  ZnO nanocrystals doped with Cd, Mg, Mn, and Fe ions were obtained by thermolysis of a family of metal cupferrates. The nanocrystals were characterized by X-ray diffraction, energy-dispersive X-ray analysis, transmission electron microscopy, UV-visible, luminescence, and excitation spectroscopy. The band gap of the nanocrystals can be tuned in the range of 2.9-3.8 eV by the use of the dopants. In most cases, the nanocrystals are sufficiently defect-free to exhibit band edge luminescence.