4-羟基-苯甲酸2,2,3,3-四氟-丙基酯 | 238751-63-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-羟基-苯甲酸2,2,3,3-四氟-丙基酯
• 英文名称: 4-Hydroxy-benzoic acid 2,2,3,3-tetrafluoro-propyl ester
• 英文别名: 2,2,3,3-tetrafluoropropyl 4-hydroxybenzoate
• CAS: 238751-63-8
• 化学式: C₁₀H₈F₄O₃
• 分子量: 252.165
• InChiKey: YGEVQEXZCKHLCD-UHFFFAOYSA-N

物化性质

• 沸点：
  299.1±40.0 °C(Predicted)
• 密度：
  1.393±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4-羟基-苯甲酸2,2,3,3-四氟-丙基酯 在 bis-triphenylphosphine-palladium(II) chloride 4-二甲氨基吡啶 、 copper(l) iodide 、 N,N'-二环己基碳二亚胺 、 三苯基膦 作用下， 以 四氢呋喃 、 三乙胺 为溶剂， 生成
  参考文献：
  名称：

  Mesomorphic Properties of a Homologous Series of Liquid Crystals with Short Fluorocarbon Chain

  摘要：

  A homologous series of short fluorocarbon chain-containing liquid crystals has been synthesized. Several of them show the phase sequence N --> SmA --> SmC in the cooling process from the isotropic liquid. The mesomorphic properties have been studied by polarizing microscopy and DSC measurements. The thermostability of SmC phases was enhanced along with the lengthening of fluorocarbon chains.

  DOI：

  10.1080/10587250210547
• 作为产物：
  描述：

  4-苯甲氧基苯甲酸 在 palladium on activated charcoal 4-二甲氨基吡啶 、 氢气 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 乙酸乙酯 为溶剂， 生成 4-羟基-苯甲酸2,2,3,3-四氟-丙基酯
  参考文献：
  名称：

  Mesomorphic Properties of a Homologous Series of Liquid Crystals with Short Fluorocarbon Chain

  摘要：

  A homologous series of short fluorocarbon chain-containing liquid crystals has been synthesized. Several of them show the phase sequence N --> SmA --> SmC in the cooling process from the isotropic liquid. The mesomorphic properties have been studied by polarizing microscopy and DSC measurements. The thermostability of SmC phases was enhanced along with the lengthening of fluorocarbon chains.

  DOI：

  10.1080/10587250210547

文献信息

• Callimatic and T-shaped liquid crystalline compounds with fluorinated terminal groups
  作者：V. V. Zuev

  DOI：10.1134/s1070363208090119

  日期：2008.9

  A series of liquid crystalline polyesters with a rigid T-shaped or a stick-like mesogenic fragment and fluorinated terminal groups of various structures was synthesized and studied by means of polarization optical microscopy, differential scanning calorimetry, and IR and H-1 NMR spectroscopy. It was shown that the effect of the fluorinated group on the thermostability of the mesophase depends on the shape of the mesogenic fragment. The thermostability of the mesophase in callimatic liquid crystalline compounds with perfluorinated terminal groups is higher and in those with difluoromethyl terminal groups containing one hydrogen atom is lower compared with their alkyl analogs. This is connected with the possibility of weak hydrogen bonding that destroys the liquid crystalline order. The thermostability of the mesophase in compounds with a T-shaped mesogenic fragment and any fluorinated terminal groups is always higher compared with their alkyl analogs.
• Mesomorphic Properties of a Homologous Series of Liquid Crystals with Short Fluorocarbon Chain
  作者：Y. G. Yang、G. Tang、J. X. Wen

  DOI：10.1080/10587250210547

  日期：2002.1.1

  A homologous series of short fluorocarbon chain-containing liquid crystals has been synthesized. Several of them show the phase sequence N --> SmA --> SmC in the cooling process from the isotropic liquid. The mesomorphic properties have been studied by polarizing microscopy and DSC measurements. The thermostability of SmC phases was enhanced along with the lengthening of fluorocarbon chains.