heptane-1,1-diylbis(benzylsulfane) | 344873-44-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: heptane-1,1-diylbis(benzylsulfane)
• 英文别名: 1-Benzylsulfanylheptylsulfanylmethylbenzene
• CAS: 344873-44-5
• 化学式: C₂₁H₂₈S₂
• 分子量: 344.585
• InChiKey: QZPMKFOXSAOQNH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  23
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  heptane-1,1-diylbis(benzylsulfane) 生成 庚醛
  参考文献：
  名称：

  EL-WASSIMY, M. T. M.;JORGENSEN, K. A.;LAWESSON, S. -O., J. CHEM. SOC. PERKIN TRANS., 1983, N 9, 2201-2203

  摘要：

  DOI：
• 作为产物：
  描述：

  1-庚炔 、 苄硫醇 在 calcium bis(1,1,2,2,3,3,4,4,4-nonafluorobutanesulfonate) 作用下， 以 乙二醇二乙醚 为溶剂， 反应 0.12h， 以76%的产率得到heptane-1,1-diylbis(benzylsulfane)
  参考文献：
  名称：

  Calcium-Catalyzed Bis-hydrothiolation of Unactivated Alkynes Providing Dithioacetals

  摘要：

  Bis-hydrothiolation of alkynes providing anti-Markovnikov dithioacetals is reported. Lewis-acidic Ca(OSO2C4F9)(2) (Ca(ONf)(2)) was synthesized for the first time and was shown to be an excellent catalyst for the transformation. The reaction is highly selective and has a wide substrate scope. It was revealed that vinyl sulfides were intermediates for this transformation and that Ca(ONf)(2) efficiently catalyzed the unprecedented reactions of unactivated vinyl sulfides with thiols to afford the dithioacetals in good to high yields.

  DOI：

  10.1021/om500442u

文献信息

• Silica-supported phosphorus pentoxide: a reusable catalyst for S,S-acetalization of carbonyl groups under ambient conditions
  作者：Hamid Reza Shaterian、Kobra Azizi、Nafiseh Fahimi

  DOI：10.1080/17415993.2010.542155

  日期：2011.2.1

  Phosphorus pentoxide supported on silica gel (P2O5/SiO2) efficiently acts as a highly active and reusable catalyst for cyclic and non-cyclic S,S-acetalization of a variety of carbonyl compounds under mild, solvent-free and ambient conditions. This method offers significant advantages such as high conversion, clean work-up, short reaction times and simplicity in operation.[GRAPHICS].