2,3'-Oxy-di-phenol | 112221-58-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3'-Oxy-di-phenol
• 英文别名: (2-Hydroxy-phenyl)-(3-hydroxy-phenyl)-aether；2-(3-Hydroxyphenoxy)phenol
• CAS: 112221-58-6
• 化学式: C₁₂H₁₀O₃
• 分子量: 202.21
• InChiKey: WIMQDCGHCFNDEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3'-Oxy-di-phenol 、 硫酸二甲酯 在 sodium hydroxide 作用下， 生成 1-甲氧基-2-(3-甲氧基苯氧基)苯
  参考文献：
  名称：

  Depsidones. II. Hydroxy and Methoxy Analogs¹

  摘要：

  DOI：

  10.1021/ja01140a045
• 作为产物：
  描述：

  2-氯-4-甲氧基-苯甲酸甲酯 在 氢溴酸 、 sodium methylate 、 铜 、 溶剂黄146 作用下， 生成 2,3'-Oxy-di-phenol
  参考文献：
  名称：

  Depsidones. II. Hydroxy and Methoxy Analogs¹

  摘要：

  DOI：

  10.1021/ja01140a045

文献信息

• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Preparation of polyarylates
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0005858A1

  公开（公告）日：1979-12-12

  High molecular weight, thermally stable polyarylates are prepared directly from dihydric phenols, aromatic dibasic acids and a chlorinating agent without isolating an acyl halide intermediate. An organic phosphite can be added to reduce color formation. This application is a Continuation-In-Part of copending Patent Application Serial No. 911,526, filed June 1, 1978.

  高分子量、热稳定性聚芳酸酯可直接由二元苯酚、芳香族二元酸和氯化剂制备而成，无需分离酰卤中间体。可添加有机亚磷酸酯以减少颜色的形成。 本申请是 1978 年 6 月 1 日提交的专利申请序列号 911,526 的部分延续。
• End-capped polyarylene polyethers, articles made therefrom and process for preparing such polyarylene polyethers
  申请人：AMOCO CORPORATION

  公开号：EP0106023A2

  公开（公告）日：1984-04-25

  Class of high performance thermosetting materials composed of polyarylene polyether resins having each of their ends capped with a monovalent unsaturated organo radical. The end-capped polyarylene polyether resins have the formula: wherein Z and Z' are each a monovalent unsaturated organo radical. Usually Z and Z' are alkylene, aralkylene or cycloalkylene moieties. The end-capped polyarylene polyethers can be cured as is or in the presence of one or more unsaturated comonomers to afford homopolymers or copolymers, respectively. Such cured systems exhibit high glass transition temperatures, good tensile properties, excellent electric and alkali resistance and improved stress cracking resistance. End- terminated polysulfone resins having molecular weight of 5,00 to 15.000 are especially advantageous. The properties exhibited by the vinyl/allyl terminated oligomers are useful in fields which require high temperature performance, excellent solvent resistance and good fabrication characteristics. Specific areas of application include high performance molded products for appliances and electronics, high temperature laminates and adhesives and protective and insulative coatings.

  一类高性能热固性材料，由聚芳醚树脂组成，每种树脂的末端都有一个一价不饱和有机基。末端封端的聚芳基聚醚树脂的结构式如下 其中 Z 和 Z'各为一价不饱和有机基。通常 Z 和 Z' 为亚烷基、芳烷基或环烷基。末端封端的聚芳基醚可以原样固化，也可以在一种或多种不饱和共聚单体的存在下固化，分别生成均聚物或共聚物。这种固化体系具有较高的玻璃化转变温度、良好的拉伸性能、优异的耐电和耐碱性能以及更强的抗应力开裂性能。分子量在 5,00 至 15,000 之间的端末端聚砜树脂尤其具有优势。乙烯基/烯丙基端接低聚物所表现出的特性适用于需要高温性能、优异的耐溶剂性和良好的制造特性的领域。 具体应用领域包括用于电器和电子产品的高性能模塑产品、高温层压板和粘合剂以及保护性和绝缘性涂层。
• Improved process for preparing poly(ether-amide)polymeric compositions
  申请人：Ashland Oil, Inc.

  公开号：EP0215239A1

  公开（公告）日：1987-03-25

  A process comprising copolymerizing an oxazoline with a bis-or poly-phenolic compound in the presence of a catalyst which is a cationic complex of an alkali or an alkaline earth metal at a temperature in the range of from about 100 to 200°C. is described.

  描述了一种工艺，包括在催化剂（碱金属或碱土金属的阳离子络合物）存在下，在约 100 至 200°C 的温度范围内，使噁唑啉与双酚或多酚化合物共聚。
• Silicone-modified polyester resin and silicone-sheathed polyester fibers made therefrom
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0214658A2

  公开（公告）日：1987-03-18

  Polyester resin is modified with siloxane block polymers in such a manner so as to form silicone-modified polyester copolymer domains of controlled size and distribution dispersed in the polyester matrix. These domains undergo microphase segregation and migration during the melt spinning and cold-drawing to the surface of the polyester fiber being formed so as to provide a silicone-sheathed polyester fiber.

  聚酯树脂用硅氧烷嵌段聚合物进行改性，以形成硅改性聚酯共聚物畴，其大小和分布可控，分散在聚酯基体中。这些畴在熔融纺丝和冷拔过程中发生微相分离并迁移到正在形成的聚酯纤维表面，从而形成硅热聚酯纤维。