bis(N-2-methylphenyl-salicyldenaminato)copper(II) | 31204-81-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(N-2-methylphenyl-salicyldenaminato)copper(II)
• 英文别名: bis(N-2-methylphenylsalicylidenaminato)copper(II)
• CAS: 31204-81-6
• 化学式: C₂₈H₂₄CuN₂O₂
• 分子量: 484.057
• InChiKey: GSDNBFZKVXUEQI-ZQSWXEMLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(N-2-methylphenyl-salicyldenaminato)copper(II) 在 乙酰丙酮 作用下， 以 further solvent(s) 为溶剂， 生成 copper acetylacetonate
  参考文献：
  名称：

  Elias, Horst; Hasserodt-Taliaferro, Christina; Hellriegel, Ludwig, Inorganic Chemistry, 1985, vol. 24, # 20, p. 3192 - 3198

  摘要：

  DOI：
• 作为产物：
  描述：

  (6E)-6-[[(2-甲基苯基)氨基]亚甲基]环己-2,4-二烯-1-酮 、 copper(II) nitrate trihydrate 以 甲醇 为溶剂， 反应 1.0h， 以40%的产率得到bis(N-2-methylphenyl-salicyldenaminato)copper(II)
  参考文献：
  名称：

  Electrocatalytic measurement of H2O2 concentration using bis(N-2-methylphenyl alicyldenaminato)copper(II) spiked in a carbon paste electrode

  摘要：

  The electrochemical behavior of a bis(N-2-methylphenyl-salicyldenaminato)copper(II) complex spiked in a carbon paste electrode (BMPSCu-CPE) and its electrocatalytic reduction of H2O2 were examined using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry. Cyclic voltammetry was used to study the redox properties of BMPSCu-CPE at various potential scan rates. The apparent charge transfer rate constant and the transfer coefficient for the electron transfer between BMPSCu and the carbon paste electrode (CPE) were 1.9 +/- 0.1 s(-1) and 0.43, respectively. BMPSCu-CPE had excellent electrocatalytic activity for H2O2 reduction in 0.1 mol/L phosphate buffer solution (pH 5.0), and it decreased the overpotential by 300 mV as compared to CPE alone. The diffusion coefficient and kinetic parameters such as the heterogeneous catalytic electron transfer rate constant and electron transfer coefficient for the reduction of H2O2 at the BMPSCu-CPE surface were also determined using electrochemical methods. Differential pulse voltammetry showed two linear dynamic ranges of 1.0-10.0 and 10.0-300.0 mu mol/L and a detection limit of 0.63 pmol/L H202. The BMPSCu-CPE has excellent reproducibility and long term stability, and it was successfully applied for the determination of H2O2 in two pharmaceutical samples: an antiseptic solution and a hair dying cream. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s1872-2067(12)60753-0

文献信息

• Synthesis, crystal structure and electronic properties of bis(N-2-bromophenyl-salicydenaminato)copper(II) complex
  作者：Rasoul Vafazadeh、Vahid Hayeri、Anthony C. Willis

  DOI：10.1016/j.poly.2010.02.030

  日期：2010.5

  A new series of complexes of the type bis(N-substituted-salicydenaminato)copper(II) (1–9), have been synthesized and characterized by IR, UV–Vis and elemental analysis methods. The molecular structure of bis(N-2-bromophenyl-salicydenaminato)copper(II) (6), was determined using X-ray crystallography. There are two independent molecules in the structure. Each shows a neutral, mononuclear, four-coordinate

  合成了一系列新的双（N-取代-水杨酰胺基）铜（II）（1-9）型配合物，并通过红外，紫外-可见和元素分析方法对其进行了表征。使用X射线晶体学测定了双（N-2-溴苯基-水杨酰胺基）铜（II）（6）的分子结构。结构中有两个独立的分子。每个都显示一个中性，单核，四坐标，方形的反式Cu [N 2 O 2几何形状，并且每个Cu原子和连接原子是共面的。分子1的螯合N–Cu–O角为91.39（11）°，分子2的螯合N–Cu–O角为91.20（11）°，而非螯合的N–Cu–O角为88.61（11）和88.80（11）°，分别。反式-N-Cu-N和反式-O-Cu-O的键角为180°。铜（II）配合物（1–9）的电子吸收光谱表明，d–d能带取决于水杨基亚胺配体苯环上取代基的性质和位置。测量了各种溶剂的UV-Vis光谱，并报道了吸收光谱和溶剂介电常数之间的关系。
• Dubey, Raj Kumar; Mishra, Sharad Kumar; Jha, Ashok Kumar, Journal of the Indian Chemical Society, 2018, vol. 95, # 5, p. 527 - 532
  作者：Dubey, Raj Kumar、Mishra, Sharad Kumar、Jha, Ashok Kumar、Kumar, Manoj

  DOI：——

  日期：——
• Sobola, Abdullahi Owolabi; Watkins, Gareth Mostyn; Van Brecht, Bernadus, South African Journal of Chemistry, 2014, vol. 67, p. 45 - 51
  作者：Sobola, Abdullahi Owolabi、Watkins, Gareth Mostyn、Van Brecht, Bernadus

  DOI：——

  日期：——