| 174843-26-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 174843-26-6
• 化学式: C₇H₁₁N₃O₄SZn
• 分子量: 298.638
• InChiKey: WJLCDMADXISERT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) chloride 、 DL-丙氨酸 、 2-硫脲嘧啶 在 NaOH 作用下， 以78%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Complexes of Copper(II), Nickel(II), Cobalt(II) and Zinc(II) with Alanine and Uracil or 2-Thiouracil

  摘要：

  Mixed ligand complexes of Cu(II), Ni(II), Co(II) and Zn(II) formed with alanine and uracil or 2-thiouracil have been synthesized and characterized by elemental analyses, conductance, spectra (IR and electronic) and magnetochemical measurements. The results show that alanine is bidentate in all cases coordinating through - NH2 and COO- groups. Uracil behaves as a bidentate ligand in the Cu(II) complex, coordinating through one carbonyl oxygen and nitrogen, whereas in other cases it is only monodentate, coordinating through nitrogen. With thiouracil, coordination occurs from carbonyl oxygen and one nitrogen in the Cu(II) and Ni(II) complexes, but in the Co(II) complex coordination occurs from thionyl sulphur and nitrogen. In the Zn(II) complex it shows tridentate behaviour, coordinating through oxygen, sulphur and nitrogen. Mixed Cu(II), Co(II) and Zn(II) complexes of uracil and the Ni(II) and Zn(II) complexes with thiouracil are octahedral, whereas the mixed Ni(II) complex with uracil shows distorted tetrahedral geometry, and the mixed Co(II) thiouracil complex is square planar. The mixed Cu(II) thiouracil complex has a binuclear structure, with square planar arrangement around each copper atom.

  DOI：

  10.1080/00945719608004266