[Co(4,4'-bis(1H-imidazol-1-yl-methyl)biphenyl)(1,2-benzenedicarboxylate)]*H2O | 1443149-48-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Co(4,4'-bis(1H-imidazol-1-yl-methyl)biphenyl)(1,2-benzenedicarboxylate)]*H2O
• CAS: 1443149-48-1
• 化学式: C₈H₄O₄*C₂₀H₁₈N₄*Co*H₂O
• 分子量: 555.516
• InChiKey: NXWXRWOUCBXIGY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.43
• 重原子数：
  38.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  147.4
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  [Co(4,4'-bis(1H-imidazol-1-yl-methyl)biphenyl)(1,2-benzenedicarboxylate)]*H2O 生成 cobalt(II) oxide
  参考文献：
  名称：

  Two novel 2-fold interpenetration frameworks constructed by 4,4′-bis(1H-imidazol-1-yl-methyl)biphenyl cobalt(II) coordination polymer and the effect of dicarboxylic acid

  摘要：

  To investigate the construction of interpenetrating frameworks, two novel coordination polymers [Co(bimb)(3)](NO3)(2)center dot 2H(2)O (1) and [Co(bimb)(bdc)]center dot H2O (2) [bimb = 4,4'-bis(1H-imidazol-1-yl-methyl)biphenyl; H(2)bdc = 1,2-benzenedicarboxylic acid] were hydrothermally synthesized and characterized by elemental analysis, IR, PXRD and TGA. Complex 1 shows a 2-fold pcu interpenetrating framework. However, complex 2 exhibits a rare 2-fold uoc interpenetrating framework due to the introduction of bdc anion. The results indicate that the presence of the second ligand could tune the product structures. Photoluminescence properties of complexes 1 and 2 reveal the cobalt ion disturbed ligand emission. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.03.046
• 作为产物：
  描述：

  cobalt(II) nitrate hexahydrate 、 水 、 邻苯二甲酸 、 4,4'-bis-(1H-imidazol-1-yl-methyl)biphenyl 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 72.0h， 以32%的产率得到[Co(4,4'-bis(1H-imidazol-1-yl-methyl)biphenyl)(1,2-benzenedicarboxylate)]*H2O
  参考文献：
  名称：

  Two novel 2-fold interpenetration frameworks constructed by 4,4′-bis(1H-imidazol-1-yl-methyl)biphenyl cobalt(II) coordination polymer and the effect of dicarboxylic acid

  摘要：

  To investigate the construction of interpenetrating frameworks, two novel coordination polymers [Co(bimb)(3)](NO3)(2)center dot 2H(2)O (1) and [Co(bimb)(bdc)]center dot H2O (2) [bimb = 4,4'-bis(1H-imidazol-1-yl-methyl)biphenyl; H(2)bdc = 1,2-benzenedicarboxylic acid] were hydrothermally synthesized and characterized by elemental analysis, IR, PXRD and TGA. Complex 1 shows a 2-fold pcu interpenetrating framework. However, complex 2 exhibits a rare 2-fold uoc interpenetrating framework due to the introduction of bdc anion. The results indicate that the presence of the second ligand could tune the product structures. Photoluminescence properties of complexes 1 and 2 reveal the cobalt ion disturbed ligand emission. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.03.046