pentylammonium nitrate | 87478-70-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: pentylammonium nitrate
• 英文别名: Nitric acid;pentan-1-amine
• CAS: 87478-70-4
• 化学式: C₅H₁₃N*HNO₃
• 分子量: 150.178
• InChiKey: IIBDEMFWVLNUAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.79
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  92.1
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-氨基戊烷 在 硝酸 作用下， 以 甲醇 为溶剂， 38.0 ℃ 、100.0 Pa 条件下， 生成 pentylammonium nitrate
  参考文献：
  名称：

  Protic ionic liquids (PILs) nanostructure and physicochemical properties: development of high-throughput methodology for PIL creation and property screens

  摘要：

  为了制备和干燥一系列的质子离子液体（PILs），开发了一种高通量方法，可以从48种Brønsted酸碱组合中制备。

  DOI：

  10.1039/c4cp04241g

文献信息

• Diversity Observed in the Nanostructure of Protic Ionic Liquids
  作者：Tamar L. Greaves、Danielle F. Kennedy、Stephen T. Mudie、Calum J. Drummond

  DOI：10.1021/jp103863z

  日期：2010.8.12

  The nanostructure of a series of 20 protic ionic liquids (PILs) has been investigated using small- and wide-angle X-ray scattering (SAXS and WAXS). The PILs contained alkylammonium, dialkylammonium, trialkylammonium, and cyclic ammonium cations combined with organic or inorganic anions. The presence of hydroxyl and methoxy substituents on the alkyl chains of the cations was also explored Many of the PILs showed a nanostructure resulting from segregation of the polar and nonpolar components of the ionic liquid It was found that this segregation was enhanced for longer alkyl chains, with a corresponding increase in the length scale, whereas the presence of hydroxyl groups on the alkyl chains led to much less ordered liquids. The broad range of protic ionic liquids studied allowed several structure property relationships to be established. The solvophobic effect was shown to be dependent on the nanostructure of the PILs. These PILs support amphiphile self-assembly, and it was shown that the less structured PILs had more "water-like" behavior in the diversity of lyotropic liquid-crystal phases supported, and the thermal stability ranges for these phases