9,9-bis(4-(3-(hydroxy)-4-aminophenoxy)phenyl)fluorene | 359642-31-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-bis(4-(3-(hydroxy)-4-aminophenoxy)phenyl)fluorene
• 英文别名: 9,9-bis[4-(4-amino-3-hydroxylphenoxy)phenyl]fluorene；9,9’-bis [4-(4-amino-2-hydroxyphenoxy)phenyl]fluorene；BAHPF；9,9-bis(4-[(4-amino-3-hydroxy)phenoxy]phenyl)fluorene；2-Amino-5-[4-[9-[4-(4-amino-3-hydroxyphenoxy)phenyl]fluoren-9-yl]phenoxy]phenol
• CAS: 359642-31-2
• 化学式: C₃₇H₂₈N₂O₄
• 分子量: 564.64
• InChiKey: BFDSFQRAMPXOCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  43
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  111
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  马来酸酐 、 9,9-bis(4-(3-(hydroxy)-4-aminophenoxy)phenyl)fluorene 在 溶剂黄146 作用下， 以43 %的产率得到9,9′-bis[4-(3-hydroxy-4-maleimide phenoxy)phenyl]fluorene
  参考文献：
  名称：

  新型含烯丙基扭曲结构双马来酰亚胺的合成及性能

  摘要：

  本工作首次合成了具有烯丙基、cardo和恶嗪结构的双马来酰亚胺（ABFBMI）单体。借助傅里叶变换红外光谱（FTIR）、质子核磁共振（1 H NMR）和核磁共振碳光谱（13 C NMR）对单体进行了表征。使用差示扫描量热法 (DSC) 和原位FTIR 研究了固化动力学和聚合过程。使用热重分析（TGA）、DSC和扫描电子显微镜（SEM）来检查热性能和断口形貌。发现 ABFBMI 通过自催化固化聚合。热固性材料（聚（ABFBMI））在高温下发生结构转变，形成聚苯并恶唑树脂（cPBO-ABFBMI）。Poly(ABFBMI) 和 cPBO-ABFBMI 均具有优异的热稳定性。柔性烯丙基侧链增强了聚（ABFBMI）的韧性。稳定的扭曲非共面和烯丙基结构使得ABFBMI具有优异的溶解性和熔融加工性能。

  DOI：

  10.1016/j.tca.2023.179661
• 作为产物：
  描述：

  4-氟-1-硝基-2-(苯基甲氧基)苯 在 palladium 10% on activated carbon 、 potassium carbonate 、 一水合肼 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 9,9-bis(4-(3-(hydroxy)-4-aminophenoxy)phenyl)fluorene
  参考文献：
  名称：

  柔性，光学透明，高折射率和热稳定的聚酰亚胺-TiO 2杂化物，用于减反射涂层†

  摘要：

  在这项研究中，由新的可溶性聚（o）制备了具有高二氧化钛含量（最高50 wt％）和厚度（15μm）的柔性透明聚酰亚胺-纳米晶体-二氧化钛杂化光学薄膜。-羟基酰亚胺），并制成三层抗反射涂层。聚酰亚胺主链上的羟基可为有机-无机键合提供一个反应位点，并通过控制丁氧基钛/羟基的摩尔比形成均匀的杂化溶液。通过XRD和TEM测量证明了分散良好的纳米二氧化钛。成功获得了具有良好的表面平面性，热尺寸稳定性，可调的折射率（在633 nm处折射率为1.3-1.80）和高光学透明性的柔性杂化膜，并进一步用于制备三层减反射膜，表明其潜在的光学性能应用程序。

  DOI：

  10.1039/c3ra42180e

文献信息

• Bis-o-aminophenols and o-aminophenolcarboxylic acids and process for preparing the same
  申请人：——

  公开号：US20020010370A1

  公开（公告）日：2002-01-24

  Bis-o-aminophenols and o-aminophenolcarboxylic acids have the following structures: 1 A 1 to A 7 are, independently of each other, H, F, CH 3 , CF 3 , OCH 3 or OCF 3 . T is an aromatic or heterocyclic residue. A method for preparing bis-o-aminophenols and o-aminophenolcarboxylic acids is also provided.

  Bis-o-aminophenols和o-aminophenolcarboxylic acids具有以下结构：1A1到A7是H，F，CH3，CF3，OCH3或OCF3，彼此独立。 T是芳香族或杂环残基。还提供了制备Bis-o-aminophenols和o-aminophenolcarboxylic acids的方法。
• Precursor of a heat resistant resin, heat resistant resin, insulating film and semiconductor device
  申请人：——

  公开号：US20020013443A1

  公开（公告）日：2002-01-31

  A precursor of a polybenzoxazole resin which comprises a crosslinking group in a molecule and has a specific structure, a polybenzoxazole resin obtained from the precursor by the condensation reaction and the crosslinking reaction, an insulating film comprising the polybenzoxazole resin and a semiconductor device comprising an insulating interlayer film in multi-layer wiring or a film for protecting surfaces which comprises the above insulating film. The precursor exhibits excellent processability due to excellent solubility in solvents and, after the ring closure, excellent heat stability in applications. The resin exhibits excellent electric, physical and mechanical properties and is advantageously used for insulating interlayer films of semiconductor devices and the like applications.

  一种聚苯并咪唑树脂的前体，其分子中包含交联基团并具有特定的结构，通过缩合反应和交联反应获得的聚苯并咪唑树脂，包括聚苯并咪唑树脂的绝缘膜以及包括上述绝缘膜的多层布线中的绝缘中间层膜或用于保护表面的膜的半导体器件。由于前体在溶剂中具有优异的溶解性，因此表现出优异的加工性能，并且在环闭后具有优异的热稳定性能，树脂表现出优异的电学、物理和机械性能，可优点地用于半导体器件的绝缘中间层膜等应用。
• Material for an insulating film, coating varnish for an insulating film, and insulating film and semiconductor device using the same
  申请人：——

  公开号：US20040002572A1

  公开（公告）日：2004-01-01

  A material for an insulating film which comprises a copolymer obtained by reacting a polyamide having a specific structure and a reactive oligomer as a component forming the film; a coating varnish for an insulating film which comprises this material and an organic solvent; an insulating film which comprises a layer of a resin comprising as a main structure a polybenzoxazole which is obtained by treating the above material or the above coating varnish by heating so that condensation reaction and crosslinking reaction take place and has fine pores; and a semiconductor device which comprises an insulating interlayer film for multi-layer wiring comprising the insulating film and/or a surface protective film comprising the insulating film. Excellent electrical, thermal and mechanical properties are exhibited and a low permittivity can be achieved.

  一种绝缘薄膜材料，包括由特定结构的聚酰胺和反应性低聚物作为成膜组分所反应得到的共聚物；一种用于绝缘薄膜的涂覆清漆，包括该材料和有机溶剂；一种绝缘薄膜，包括一层树脂，其主要结构为通过热处理上述材料或上述涂覆清漆得到的聚苯并咪唑，发生缩聚反应和交联反应并具有细小孔隙；以及一种半导体器件，包括用于多层布线的绝缘中间层膜，包括上述绝缘薄膜和/或表面保护膜，包括上述绝缘薄膜。具有优异的电性能、热性能和机械性能，并且可以实现低介电常数。
• Benzoxazole Resin Precursor, Polybenzoxazole Resin, Resin Film And Semiconductor Device
  申请人：Enoki Takashi

  公开号：US20080206548A1

  公开（公告）日：2008-08-28

  A benzoxazole resin precursor comprising a first repeating unit which is obtained by the reaction of a bisaminophenol compound and a dicarboxylic acid compound, at least one of which has the diamondoid structure; a benzoxazole resin precursor further comprising a second repeating unit which is obtained by the reaction of a bisaminophenol compound having no diamondoid structure and a dicarboxylic acid compound having no diamondoid structure; a polybenzoxazole resin obtained by the ring-closing reaction with dehydration of the above benzoxazole resin precursor; a resin film constituted with the benzoxazole resin precursor or the polybenzoxazole resin. A polybenzoxazole resin and a resin film having excellent heat resistance and a small permittivity and a semiconductor device using the resin film can be obtained from the benzoxazole resin precursor.

  一种苯并噁唑树脂前体，包括第一重复单元，该单元由双氨基酚化合物和二羧酸化合物反应得到，其中至少一个具有金刚烷结构；一种苯并噁唑树脂前体，进一步包括第二重复单元，该单元由不具有金刚烷结构的双氨基酚化合物和不具有金刚烷结构的二羧酸化合物反应得到；通过上述苯并噁唑树脂前体的环合反应和脱水反应得到的聚苯并噁唑树脂；由苯并噁唑树脂前体或聚苯并噁唑树脂构成的树脂膜。可以从苯并噁唑树脂前体中获得具有优异耐热性和小介电常数的聚苯并噁唑树脂和树脂膜，以及使用树脂膜的半导体器件。
• Resin Composition, Varnish, Resin Film and Semiconductor Device
  申请人：Enoki Takashi

  公开号：US20090214860A1

  公开（公告）日：2009-08-27

  Disclosed is a resin composition comprising a benzoxazole resin precursor having a first repeating unit obtained by reacting a bisaminophenol compound and a dicarboxylic acid compound, and a cross-linking agent wherein at least one of the bisaminophenol compound and the dicarboxylic acid compound has a diamondoid structure. The benzoxazole resin precursor further comprises a second repeating unit obtained by reacting a bisaminophenol compound not having a diamondoid structure and a dicarboxylic acid compound not having a diamondoid structure. Also disclosed is a resin film comprising the resin composition.

  本发明公开了一种树脂组合物，包括一种苯并噁唑树脂前体，其具有通过反应双氨基酚化合物和二羧酸化合物得到的第一重复单元，以及交联剂，其中双氨基酚化合物和/或二羧酸化合物中至少有一个具有金刚烷结构。苯并噁唑树脂前体还包括通过反应不具有金刚烷结构的双氨基酚化合物和不具有金刚烷结构的二羧酸化合物得到的第二重复单元。此外，本发明还公开了一种包括该树脂组合物的树脂膜。