1,3,5-tris((4'-hydroxyphenyl)carbamoyl)benzene | 1216665-32-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3,5-tris((4'-hydroxyphenyl)carbamoyl)benzene
• 英文别名: 1-N,3-N,5-N-tris(4-hydroxyphenyl)benzene-1,3,5-tricarboxamide
• CAS: 1216665-32-5
• 化学式: C₂₇H₂₁N₃O₆
• 分子量: 483.48
• InChiKey: OWPOKGNTSSKCMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  148
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,3,5-tris((4'-hydroxyphenyl)carbamoyl)benzene 、 4-硝基苯甲酰氯 在 三乙胺 作用下， 以 N-甲基吡咯烷酮 为溶剂， 以92%的产率得到[4-[[3,5-Bis[(4-hydroxyphenyl)carbamoyl]benzoyl]amino]phenyl] 4-nitrobenzoate
  参考文献：
  名称：

  Synthesis and properties of hyperbranched polyamide–esters derived from 1,3,5-tris(4′-hydroxyphenylcarbamoyl)benzene

  摘要：

  A novel aromatic triol was synthesized and polycondensed with various diacid chlondes resulting in the preparation of a series of hydroxy-terminated hyperbranched polyamide-esters without gelation Structure and degree of branching of the ensuing polymers were confirmed by FTIR. H-1 and C-13 NMR analyses These thermally stable polymers were found to be Soluble in apiotic solvents Inherent vis and T-g values lie in the range of 0 15-0 21 dL/g and 74-112 degrees C, respectively (C) 2009 Elsevier Ltd All rights ieserved

  DOI：

  10.1016/j.tet.2009.11.108
• 作为产物：
  描述：

  1,3,5-苯三甲酰氯 、 对氨基苯酚 在 methyloxirane 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 6.5h， 以96%的产率得到1,3,5-tris((4'-hydroxyphenyl)carbamoyl)benzene
  参考文献：
  名称：

  Synthesis and properties of hyperbranched polyamide–esters derived from 1,3,5-tris(4′-hydroxyphenylcarbamoyl)benzene

  摘要：

  A novel aromatic triol was synthesized and polycondensed with various diacid chlondes resulting in the preparation of a series of hydroxy-terminated hyperbranched polyamide-esters without gelation Structure and degree of branching of the ensuing polymers were confirmed by FTIR. H-1 and C-13 NMR analyses These thermally stable polymers were found to be Soluble in apiotic solvents Inherent vis and T-g values lie in the range of 0 15-0 21 dL/g and 74-112 degrees C, respectively (C) 2009 Elsevier Ltd All rights ieserved

  DOI：

  10.1016/j.tet.2009.11.108

文献信息

• METHOD OF PREPARING RETARDATION FILM, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY
  申请人：Konica Minolta, Inc.

  公开号：US20150114257A1

  公开（公告）日：2015-04-30

  A method of preparing a retardation film includes cellulose acetate having an average degree of acetylation of 2.0 to 2.5 and having a moisture content of 1.0 mass % or less, where the retardation film includes a compound having a Van der Waals volume of 450 to 1000 Å3. The retardation film is prepared by a dope preparing step of dissolving cellulose acetate having an average degree of acetylation within the range of 2.0 to 2.5 to prepare a dope; a film product forming step of casting the dope onto a metal belt to form a film product; a film product peeling step of peeling off the film product from the metal belt; a drawing step of drawing the peeled film product; and a drying step at a drying temperature of 140° C. or more.
• Synthesis and properties of hyperbranched polyamide–esters derived from 1,3,5-tris(4′-hydroxyphenylcarbamoyl)benzene
  作者：Saima Shabbir、Sonia Zulfiqar、Zahoor Ahmad、Muhammad Ilyas Sarwar

  DOI：10.1016/j.tet.2009.11.108

  日期：2010.2

  A novel aromatic triol was synthesized and polycondensed with various diacid chlondes resulting in the preparation of a series of hydroxy-terminated hyperbranched polyamide-esters without gelation Structure and degree of branching of the ensuing polymers were confirmed by FTIR. H-1 and C-13 NMR analyses These thermally stable polymers were found to be Soluble in apiotic solvents Inherent vis and T-g values lie in the range of 0 15-0 21 dL/g and 74-112 degrees C, respectively (C) 2009 Elsevier Ltd All rights ieserved