3,5-Dinitrophenolate | 15573-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-Dinitrophenolate
• CAS: 15573-51-0
• 化学式: C₆H₃N₂O₅
• 分子量: 183.1
• InChiKey: UEMBNLWZFIWQFL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  115
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2,4-Dinitrophenylacetat 、 苯氧基自由基 以 水 为溶剂， 生成 3,5-Dinitrophenolate 、 乙酸苯酯
  参考文献：
  名称：

  Concerted acetyl-group transfer between substituted phenolate ion nucleophiles: variation of transition-state structure as a function of substituent

  摘要：

  DOI：

  10.1021/ja00189a045

文献信息

• METALPORPHYRIN COMPLEX, PREPARATION METHOD THEREFOR AND METHOD FOR PREPARING POLYCARBONATE
  申请人：CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESDE ACADEMY OF SCIENCES

  公开号：US20160194346A1

  公开（公告）日：2016-07-07

  The present invention provides a metalporphyrin complex having structure represented by formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are independently selected from one of hydrogen, halogen, aliphatic group, substituted heteroaliphatic group, aryl and substituted heteroaryl; n is 1-6; L is quaternary ammonium functional group or quaternary phosphonium functional group; M is a metal element; and X is one of halogen, —NO 3 , BF 4 —, —CN, p-methyl benzoate, o-nitrophenol oxygen anion, 2,4-dinitrophenol oxygen anion, 2,4,6-trinitrophenol oxygen anion, 3,5-dichlorophenol oxygen anion and pentafluorophenol oxygen anion. The metalporphyrin complex provided in the present invention has two quaternary ammonium functional groups or two quaternary phosphonium functional groups, and compared with the prior art, the metalporphyrin complex shows higher catalytic activity in catalyzing polymerization reaction of carbon dioxide and an epoxide.

  本发明提供了一种金属卟啉配合物，其结构由式（I）表示，其中R1、R2、R3、R4、R5、R6、R7、R8、R9和R10分别独立地选自氢、卤素、脂肪基、取代杂脂肪基、芳基和取代杂芳基中的一种；n为1-6；L为季铵功能基或季磷功能基；M为金属元素；X为卤素、—NO3、BF4—、—CN、对甲基苯甲酸酯、邻硝基酚氧阴离子、2,4-二硝基酚氧阴离子、2,4,6-三硝基酚氧阴离子、3,5-二氯酚氧阴离子和五氟苯酚氧阴离子中的一种。本发明提供的金属卟啉配合物具有两个季铵功能基或两个季磷功能基，与现有技术相比，金属卟啉配合物在催化二氧化碳和环氧化合物的聚合反应中显示出更高的催化活性。
• METHODS (AMACR)
  申请人：UNIVERSITY OF BATH

  公开号：US20170176436A1

  公开（公告）日：2017-06-22

  A method of measuring α-methylacyl-CoA racemase (AMACR) activity in a sample is described comprising the steps of: (i) providing a sample; (ii) contacting said sample with a substrate compound that undergoes elimination of hydrogen and a leaving group catalysed by said AMACR to produce a product compound having an additional carbon-carbon double bond; and (iii) measuring the amount of said leaving group and/or of said product compound and/or of unreacted substrate compound. Also provided are methods of diagnosis and medical imaging, in particular for use in diagnosing prostate cancer. Also provided are substrate compounds of Formula 1 for use in the methods described herein.

  描述了一种测量样本中α-甲基酰辅酶A羧化酶（AMACR）活性的方法，包括以下步骤：（i）提供样本；（ii）将所述样本与底物化合物接触，该化合物经过由所述AMACR催化的氢和一个离去基团的消除产生具有额外碳-碳双键的产物化合物；以及（iii）测量所述离去基团和/或所述产物化合物和/或未反应的底物化合物的量。还提供了诊断和医学成像的方法，特别用于诊断前列腺癌。还提供了用于上述方法的Formula 1的底物化合物。
• Metalporphyrin complex, preparation method therefor and method for preparing polycarbonate
  申请人：CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES

  公开号：US10005806B2

  公开（公告）日：2018-06-26

  The present invention provides a metalporphyrin complex having structure represented by formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are independently selected from one of hydrogen, halogen, aliphatic group, substituted heteroaliphatic group, aryl and substituted heteroaryl; n is 1-6; L is quaternary ammonium functional group or quaternary phosphonium functional group; M is a metal element; and X is one of halogen, —NO3, BF4—, —CN, p-methyl benzoate, o-nitrophenol oxygen anion, 2,4-dinitrophenol oxygen anion, 2,4,6-trinitrophenol oxygen anion, 3,5-dichlorophenol oxygen anion and pentafluorophenol oxygen anion. The metalporphyrin complex provided in the present invention has two quaternary ammonium functional groups or two quaternary phosphonium functional groups, and compared with the prior art, the metalporphyrin complex shows higher catalytic activity in catalyzing polymerization reaction of carbon dioxide and an epoxide.

  本发明提供了一种金属卟啉配合物，其结构由式（I）表示，其中 R1、R2、R3、R4、R5、R6、R7、R8、R9 和 R10 独立选自氢、卤素、脂肪族、取代的杂脂肪族、芳基和取代的杂芳基中的一种；n 为 1-6；L 是季铵官能团或季鏻官能团；M 是金属元素；X 是卤素、-NO3、BF4-、-CN、对甲基苯甲酸酯、邻硝基苯酚氧阴离子、2,4-二硝基苯酚氧阴离子、2,4,6-三硝基苯酚氧阴离子、3,5-二氯苯酚氧阴离子和五氟苯酚氧阴离子中的一种。本发明提供的金属卟啉络合物具有两个季铵官能团或两个季膦官能团，与现有技术相比，金属卟啉络合物在催化二氧化碳与环氧化物的聚合反应中表现出更高的催化活性。
• PROCESS FOR THE PREPARATION OF A POLYMER COMPOSITION
  申请人：DSM N.V.

  公开号：EP0603381A1

  公开（公告）日：1994-06-29
• Methods (AMACR)
  申请人：University of Bath

  公开号：EP3102694A1

  公开（公告）日：2016-12-14