2,7-Bis(9,9-dioctylfluoren-2-yl)-9,9-bis(undec-10-enyl)fluorene | 1354686-48-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2,7-Bis(9,9-dioctylfluoren-2-yl)-9,9-bis(undec-10-enyl)fluorene
• 英文别名: 2,7-bis(9,9-dioctylfluoren-2-yl)-9,9-bis(undec-10-enyl)fluorene
• CAS: 1354686-48-8
• 化学式: C₉₃H₁₃₀
• 分子量: 1248.06
• InChiKey: AUUXJDRXZYHQRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  37.6
• 重原子数：
  93
• 可旋转键数：
  50
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  11-溴-1-十一烯 、 2-[7-(9,9-dioctylfluoren-2-yl)-9H-fluoren-2-yl]-9,9-dioctylfluorene 在 potassium hydroxide 作用下， 以 四氢呋喃 、 二甲基亚砜 为溶剂， 以80%的产率得到2,7-Bis(9,9-dioctylfluoren-2-yl)-9,9-bis(undec-10-enyl)fluorene
  参考文献：
  名称：

  Perfectly Regioregular Electroactive Polyolefins: Impact of Inter-Chromophore Distance on PLED EQE

  摘要：

  Acyclic diene metathesis polymerization (ADMET) was used to synthesize a series of perfectly regioregular polyolefins, in which the number of backbone atoms between pendant terfluorene groups was precisely controlled at 8, 14, or 20 carbons. Analogous random copolymers containing identical chromophore densities were also synthesized to study the impact of regioregularity on the performance of this class of materials in polymer light emitting diodes (PLEDs). Additionally, the backbone alkene remnants of ADMET were saturated to generate materials with somewhat different ordering. These saturated derivatives led to improvements in PLED external quantum efficiencies (EQEs) over their unsaturated analogues in most cases, with a large improvement in one material. Charge mobility, as manifested in current density during PLED characterization, and relative solid-state fluorescence quantum yield (Phi(F)) also exhibit reasonable dependencies, with longer distances between electroactive groups yielding lower PLED current densities and higher Phi(F). Regioregularity has the opposite effect, giving rise to higher current densities and lower Phi(F) as compared to regiorandom analogues.

  DOI：

  10.1021/ma202409k

文献信息

• Perfectly Regioregular Electroactive Polyolefins: Impact of Inter-Chromophore Distance on PLED EQE
  作者：Brian S. Aitken、Patrick M. Wieruszewski、Kenneth R. Graham、John R. Reynolds、Kenneth B. Wagener

  DOI：10.1021/ma202409k

  日期：2012.1.24

  Acyclic diene metathesis polymerization (ADMET) was used to synthesize a series of perfectly regioregular polyolefins, in which the number of backbone atoms between pendant terfluorene groups was precisely controlled at 8, 14, or 20 carbons. Analogous random copolymers containing identical chromophore densities were also synthesized to study the impact of regioregularity on the performance of this class of materials in polymer light emitting diodes (PLEDs). Additionally, the backbone alkene remnants of ADMET were saturated to generate materials with somewhat different ordering. These saturated derivatives led to improvements in PLED external quantum efficiencies (EQEs) over their unsaturated analogues in most cases, with a large improvement in one material. Charge mobility, as manifested in current density during PLED characterization, and relative solid-state fluorescence quantum yield (Phi(F)) also exhibit reasonable dependencies, with longer distances between electroactive groups yielding lower PLED current densities and higher Phi(F). Regioregularity has the opposite effect, giving rise to higher current densities and lower Phi(F) as compared to regiorandom analogues.