[Zn(II)(7-fluoro-12-methyl-4-oxo-1-azatricyclo[7.3.1.0(5,13)]trideca-2,5,7,9(13)-tetraene-3-carboxylate)2(H2O)2]*H2O | 1268154-95-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Zn(II)(7-fluoro-12-methyl-4-oxo-1-azatricyclo[7.3.1.0(5,13)]trideca-2,5,7,9(13)-tetraene-3-carboxylate)2(H2O)2]*H2O
• 英文别名: [Zn(II)(flumequine(-1H))2(H2O)2]*H2O
• CAS: 1268154-95-5
• 化学式: C₂₈H₂₆F₂N₂O₈Zn*H₂O
• 分子量: 639.925
• InChiKey: QKZNWIIQDAOYRB-IIQJWNTRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氟甲喹 、 zinc(II) nitrate hexahydrate 在 KOH 作用下， 以 乙醇 、 水 为溶剂， 以64%的产率得到[Zn(II)(7-fluoro-12-methyl-4-oxo-1-azatricyclo[7.3.1.0(5,13)]trideca-2,5,7,9(13)-tetraene-3-carboxylate)2(H2O)2]*H2O
  参考文献：
  名称：

  Cu(II) and Zn(II) complexes with a fluoroquinolone antibiotic: Spectroscopic and X-ray absorption characterization

  摘要：

  The synthesis of two complexes with the antibiotic flumequine, [Cu(Flumequine)(2)(OH2)(2)] (1) and [Zn(Flumequine)(2)(OH2)(2)]center dot H2O (2) is reported. Their molecular structure was elucidated by combining various spectroscopic techniques. The EPR parameters combined with XAS data underline a tetragonal distorted octahedral geometry for the two complexes. The coordination occurs through the carbonyl and carboxylate oxygen atoms in the equatorial plane. The coordination sphere is completed by two water molecules in axial position. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.11.005