Bis[1-oxo-2,5,8-tris(trifluoromethyl)tetradecafluoro-3,6,9-trioxadodecane-1-yl] peroxide | 133414-71-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Bis[1-oxo-2,5,8-tris(trifluoromethyl)tetradecafluoro-3,6,9-trioxadodecane-1-yl] peroxide
• 英文别名: [2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]propanoyl] 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]propaneperoxoate
• CAS: 133414-71-8
• 化学式: C₂₄F₄₆O₁₀
• 分子量: 1322.18
• InChiKey: CKPVOLVFDGUVOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.1
• 重原子数：
  80
• 可旋转键数：
  23
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  56

反应信息

• 作为反应物：
  描述：

  噻吩 、 Bis[1-oxo-2,5,8-tris(trifluoromethyl)tetradecafluoro-3,6,9-trioxadodecane-1-yl] peroxide 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 5.0h， 以94%的产率得到2-(perfluoro-1',4',7'-trimethyl-2',5',8'-trioxaundecyl)thiophene
  参考文献：
  名称：

  Synthesis of aromatic compounds containing perfluoro-oxa-alkyl groups

  摘要：

  Perfluoro-oxa-alkanoyl peroxides[[C3F7O(CF(CF3)CF2O)nCF(CF3)CO2]2, n = 0, 1, 2] smoothly reacted with thiophene and furan under mild conditions to affor 2-perfluoro-oxa-alkylthiophenes and furnas in good yields. Perfluoro-oxa-alkylations of benzene and pyrrole were also found to proceed by the use of these peroxides. Furthermore, these peroxides were found to be applied to direct aromatic perfluoro-oxa-alkylations of polystyrene.

  DOI：

  10.1016/s0022-1139(00)80311-5

文献信息

• A polymer comprising fluoroalkyl group, a method of preparation thereof, a surface active agent, a surface treatment agent and a coating composition
  申请人：NOF CORPORATION

  公开号：EP0537669A1

  公开（公告）日：1993-04-21

  A polymer comprising fluoroalkyl group has a structure in which one or two parts of the fluoroalkyl group at the one or both ends of the molecule are linked to a part of alkylene groups or alkylene groups substituted with halogen, a part of alkylene group substituted with functional groups, such as halogen, cyano group, alkylsulfonic acid group, amidoalkylsulfonic acid group, carboxylic acid group, carboxyl group, oxycarbonyl group, ether group, epoxy group and the like, and/or a part of silicone group. A method of preparation of the polymer comprising fluoroalkyl group contains reaction of a fluoroalkanoyl peroxide with a monomer comprising the functional group or a monomer comprising silicone group. A surface active agent comprises fluoroalkyl group and caroxylic acid salt group. A surface treatment agent comprises the polymer comprising fluoroalkyl group, hydrolysis products thereof, hydrolytic condensation products thereof, and mixtures thereof. A coating composition comprises the polymer comprising fluoroalkyl group. The polymer comprising fluoroalkyl group has excellent water repellency, oil repellency and weatherability because the fluoroalkyl group is introduced into the molecule through carbon-carbon linkage.

  包含氟烷基的聚合物具有如下结构：分子一端或两端的氟烷基的一部分或两部分与亚烷基或被卤素取代的亚烷基的一部分、被官能团（如卤素、氰基、烷基磺酸基、氨基烷基磺酸基、羧酸基、羧基、氧羰基、醚基、环氧基等）取代的亚烷基的一部分和/或硅酮基的一部分相连接。包含氟烷基的聚合物的制备方法包括过氧化氟烷酰与包含官能团的单体或包含硅酮基的单体反应。一种表面活性剂包括氟烷基和甲酸盐基。表面处理剂包括含氟烷基的聚合物、其水解产物、水解缩合产物及其混合物。一种涂料组合物，包括含氟烷基的聚合物。含氟烷基的聚合物具有优异的防水性、防油性和耐候性，因为氟烷基是通过碳-碳连接引入分子中的。
• Polyfluoroalkanoyl peroxide
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0405396B1

  公开（公告）日：1994-09-07
• JPH05982A
  申请人：——

  公开号：JPH05982A

  公开（公告）日：1993-01-08
• POWDERY SILICA COMPOSITE PARTICLES, PROCESS OF PRODUCING SAME, SILICA COMPOSITE PARTICLE DISPERSION, AND RESIN COMPOSITION
  申请人：Sawada Hideo

  公开号：US20090047518A1

  公开（公告）日：2009-02-19

  An object of the invention is to provide a substance enabling uniformly dispersing an ionic liquid or a phosphonium salt in various solvents, resin materials, and the like. A powdery silica composite particle obtained by a surface treatment step comprising providing a reaction solution by mixing a silica sol containing a core silica particle having an average particle size of 5 to 200 nm, an alkoxysilane, and an ionic liquid and hydrolyzing the alkoxysilane by addition of an acid or an alkali to the reaction solution to surface-treat the core silica particle.
• POWDERY THREE-DIMENSIONALLY CROSSLINKED CLATHRATE PARTICLE, PROCESS OF PRODUCING SAME, DISPERSION, AND RESIN COMPOSITION
  申请人：Sawada Hideo

  公开号：US20090036599A1

  公开（公告）日：2009-02-05

  A material enabling uniformly dispersing an ionic liquid or a phosphonium salt in various solvents or resin materials is provided. The material is powdery particles of a three-dimensionally crosslinked clathrate obtained by a process including a first-order polymerization step in which a fluoroalkanoyl peroxide compound, a monofunctional monomer, and a polyfunctional monomer having an olefinic double bond and an isocyanate group are reacted to one another to obtain a fluoroalkyl-containing cooligomer and a crosslinking step including the substeps of mixing the fluoroalkyl-containing cooligomer and an ionic liquid or a phosphonium salt and causing the cooligomer to react with itself at the isocyanate groups thereof in the presence of the ionic liquid or the phosphonium salt to obtain powdery three-dimensionally crosslinked clathrate particles.