zinc(II) 2,3,7,8,12,13,17,18-octa(ethoxycarbonyl)porphyrinate | 1429373-40-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: zinc(II) 2,3,7,8,12,13,17,18-octa(ethoxycarbonyl)porphyrinate
• CAS: 1429373-40-9
• 化学式: C₄₄H₄₄N₄O₁₆Zn
• 分子量: 950.241
• InChiKey: WBHSYODGAXGWKC-XTDOBPMPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octa(ethoxycarbonyl)porphyrin 、 zinc(II) acetate dihydrate 以 甲醇 、 二氯甲烷 为溶剂， 反应 4.0h， 以96%的产率得到zinc(II) 2,3,7,8,12,13,17,18-octa(ethoxycarbonyl)porphyrinate
  参考文献：
  名称：

  Synthesis and photophysical studies of a chlorin sterically designed to prevent self-aggregation

  摘要：

  Synthesis and photophysical evaluations of a new non-aggregating chlorin derivative are described. A beta-octa(carboxyethyl)porphyrin 3 was synthesized in 2 steps starting from pyrrole-3,4-dicarboxylic acid diethyl ester (2). The new chlorin derivative 6 was obtained through a 1,3-dipolar cycloaddition using benzyl azomethine ylide. Chlorin 6 presents a molecular scaffold in an "L" shape avoiding aggregation in solutions at 1-27 mM. Photophysical properties were measured, and indicate that this new compound can be considered a useful candidate for PDT studies. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.02.011