2,3-bis-benzoylamino-succinic acid | 101914-12-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2,3-bis-benzoylamino-succinic acid
• 英文别名: 2,3-Bis-benzoylamino-bernsteinsaeure；2,3-Dibenzamidobutanedioic acid
• CAS: 101914-12-9；780769-20-2
• 化学式: C₁₈H₁₆N₂O₆
• 分子量: 356.335
• InChiKey: WTVMWQGJGNVCPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  133
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3-bis-benzoylamino-succinic acid 在 氯化亚砜 作用下， 反应 2.0h， 以78%的产率得到Hippuroflavin
  参考文献：
  名称：

  [EN] NEW HETEROCYCLIC COMPOUNDS, A PROCESS FOR THEIR PREPARATION AND THEIR USE AS DYES AND PIGMENTS
  [FR] NOUVEAUX COMPOSES HETEROCYCLIQUES, PROCEDE DE PREPARATION DE CES COMPOSES ET LEUR UTILISATION EN TANT QUE COLORANTS ET PIGMENTS

  摘要：

  化合物的公式（I），其中R1是氢，羟基，卤素，硝基，氰基，氨基，羧基，羧酸酯，磺基，磺酸酯，羧酰胺，磺酰胺，烷基硫基，芳基硫基，烷氧基或芳氧基，R'1是氢，羟基，卤素，硝基，氰基，氨基，羧基，羧酸酯，磺基，磺酸酯，羧酰胺，磺酰胺，烷基硫基，芳基硫基，烷氧基或芳氧基，X是-O-，-S-，-NH-或-N（烷基）-，X'是-O-，-S-，-NH-或-N（烷基）-，Y是氢或羧酸酯，Y'是氢或羧酸酯，Z是=C-或=N-，Z'是=C-或=N-，x是0或1，当Z是=N-时，x是0，y是0或1，当Z'是=N-时，y是0，A是公式（II），（III），（IV），（V）或（VI）的共轭连接桥，其中n为0，1，2或3，m为0，1，2或3，B为苯环，T为=C（R3）-或=N-，其中R3为氢，C1-C12烷基或CN，W为未取代或取代的烷基，卤素，羟基，烷氧基，烷硫基或氨基的杂环，或线性或多缩合芳香基团，G为-CH=或-N=，R2为氢，烷基，卤素，羟基，烷氧基，烷硫基或氨基，它们的制备以及它们在生产有色塑料或聚合物颜色颗粒中的应用。

  公开号：

  WO2004089941A1
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 2,3-bis-benzoylamino-succinic acid
  参考文献：
  名称：

  Farchy; Tafel, Chemische Berichte, 1893, vol. 26, p. 1989

  摘要：

  DOI：

文献信息

• New heterocyclic compounds, a process for their preparation and their use as dyes and pigments
  申请人：Adam Jean-Marie

  公开号：US20060124014A1

  公开（公告）日：2006-06-15

  Compounds of formula (I) wherein R 1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, R′ 1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, X is —O—, —S—, —NH— or —N(alkyl)-, X′ is —O—, —S—, —NH— or —N(alkyl)-, Y is hydrogen or carboxylic ester, Y′ is hydrogen or carboxylic ester, Z is ═C— or ═N—, Z′ is ═C— or ═N—, x is 0 or 1, when Z is ═N—, then x is 0, y is 0 or 1, when Z′ is ═N—, then y is 0, A is a conjugated linking bridge of the formulae (II), (III), (IV), (V), or (VI), wherein n is 0, 1, 2 or 3, m is 0, 1, 2 or 3, B is a phenyl ring, T is ═C(R 3 )— or ═N—, wherein R 3 is hydrogen, C 1 -C 12 alkyl or CN, W is a heterocyclic, or linear or polycondensed aromatic group which is unsubstituted or substituted by alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, G is —CH═ or —N═, and R 2 is hydrogen, alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, their preparation and their use in the production of coloured plastics or polymeric color particles.

  式(I)化合物 其中 R 1 是氢、羟基、卤素、硝基、氰基、氨基、羧基、羧酸酯、磺酸酯、磺酸酰胺、羧酸酰胺、磺酸酰胺、烷硫基、芳硫基、烷氧基或芳氧基， R′ 1 是氢、羟基、卤素、硝基、氰基、氨基、羧基、羧酸酯、磺酸、磺酸酯、羧酸酰胺、磺酸酰胺、烷硫基、芳硫基、烷氧基或芳氧基，X 是-O-、-S-、-NH-或-N（烷基）-，X′ 是-O-、-S-、-NH-或-N（烷基）-，Y 是氢或羧酸酯、Y′是氢或羧酸酯，Z是═C-或═N-，Z′是═C-或═N-，x是0或1，当Z是═N-时，则x是0，y是0或1，当Z′是═N-、则 y 是 0，A 是式 (II)、(III)、(IV)、(V) 或 (VI) 的共轭连接桥，其中 n 是 0、1、2 或 3，m 是 0、1、2 或 3，B 是一个苯基环，T 是 ═C(R 3 )-或═N-，其中 R 3 是氢、C 1 -C 12 烷基或 CN，W 是未被取代或被烷基、卤素、羟基、烷氧基、烷硫基或氨基取代的杂环基团或线性或多缩合芳香基团，G 是 -CH═ 或 -N═，以及 R 2 是氢、烷基、卤素、羟基、烷氧基、烷硫基或氨基。
• Kuhn; Zumstein, Chemische Berichte, 1925, vol. 58, p. 1431
  作者：Kuhn、Zumstein

  DOI：——

  日期：——
• NEW HETEROCYCLIC COMPOUNDS, A PROCESS FOR THEIR PREPARATION AND THEIR USE AS DYES AND PIGMENTS
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1603902A1

  公开（公告）日：2005-12-14
• New compounds, a process for their preparation and their use as dyes and pigments
  申请人：Adam Jean-Marie

  公开号：US20060258784A1

  公开（公告）日：2006-11-16

  Compounds of formula (1) wherein R 1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, R′ 1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, X is —O—, —S—, —NH— or —N(alkyl)—, X′ is —O—, —S—, —NH— or —N(alkyl)—, Y is hydrogen or carboxylic ester, Y′ is hydrogen or carboxylic ester, Z is ═C— or ═N—, Z′ is ═C— or ═N—, x is 0 or 1, when Z is ═N—, then x is 0, y is 0 or 1, when Z′ is ═N—, then y is 0, A is a conjugated linking bridge of the formula wherein n is 0, 1, 2 or 3, m is 0, 1, 2 or 3, B is a phenyl ring, T is ═C(R 3 )— or ═N—, wherein R 3 is hydrogen, C 1 -C 12 alkyl or CN, W is a heterocyclic, or linear or polycondensed aromatic group which is unsubstituted or substituted by alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, G is —CH═ or —N═, and R 2 is hydrogen, alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, their preparation and their use in the production of coloured plastics or polymeric colour particles.