9,11-dodecadiene-1-yl acetate | 60428-80-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 9,11-dodecadiene-1-yl acetate
• 英文别名: 9,11-dodecadien-1-yl acetate；(cis,trans)-12-Acetoxy-1,3-dodecadien；12-Acetoxy-1,3-dodecadiene；dodeca-9,11-dienyl acetate
• CAS: 60428-80-0
• 化学式: C₁₄H₂₄O₂
• 分子量: 224.343
• InChiKey: ARPQLVHCERGNAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2915390090

反应信息

• 作为产物：
  描述：

  1-acetoxy-9-hydroxy-dodec-11-ene 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 三乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 14.0h， 生成 9,11-dodecadiene-1-yl acetate
  参考文献：
  名称：

  Combined Lewis acid catalysts in shotgun process: a convenient synthesis of the female sex pheromone of the red-bollworm moth

  摘要：

  The combined use of Lewis acid and distannoxane catalysts gives rise to a new variant of the shotgun process. The unwanted acetylation of a secondary homoallyl alcohol by the former catalyst is suppressed through hybridization with the latter resulting in one-pot aldehyde allylation and primary alcohol acetylation of omega-hydroxy alkanal without protection/deprotection procedures. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)00970-5

文献信息

• Regioreversed reactions of trimethylsilyl or phenylselenyl allylic carbanion with carbonyl compounds via allylic aluminum “ate” complexes
  作者：Yoshinori Yamamoto、Yoshikazu Saito、Kazuhiro Maruyama

  DOI：10.1016/s0040-4039(00)85663-4

  日期：1982.1

  Triethylaluminum “ate” complexes of trimethylsilyl and phenylselenyl allylic carbanion react with carbonyl compounds at the α-position either exclusively or predominantly.

  三甲基甲硅烷基和苯基硒烯基烯丙基碳负离子的三乙基铝“酸酯”配合物仅或主要与在α位的羰基化合物反应。
• Synthesis of 12-acetoxy-1, 3-dodecadiene, an insect sex pheromone of the red bollworm moth, from a butadiene telomer
  作者：T. Mandai、H. Yasuda、M. Kaito、J. Tsuji、R. Yamaoka、H. Fukami

  DOI：10.1016/0040-4020(79)80067-8

  日期：1979.1

  8-Phenoxy-1, 6-octadiene (1) formed by the Pd-catalyzed telomerization of butadiene with phonol was converted to 8-phenoxy-6-octen-1-ol (3). The alcohol 3 was converted to 8-iodo-1-phenoxy-2-octene (5). The Grignard reagent 7 prepared from 4-chloro 1-butyl tetrahydropranyl ether was coupled with the iodide 5 by the catalysis of CuI and bipyridyl to give 12-phenoxy-10-dodecen-1-ol (9), which was converted

  通过丁二烯与苯酚的钯催化端粒化反应形成的8-苯氧基-1，6-辛二烯（1）被转化为8-苯氧基-6-辛烯-1-醇（3）。醇3被转化为8-碘-1-苯氧基-2-辛烯（5）。由4-氯1-丁基四氢戊基醚制得的格氏试剂7与碘化物5通过CuI和联吡啶基的催化作用偶合，得到12-苯氧基-10-十二碳烯-1-醇（9），将其转化为12-苯氧基乙酰氧基-1-苯氧基-2-十二碳烯（10）。最后，通过钯催化从苯氧基乙酰氧基-十二碳烯（10）中除去苯酚，获得了12-乙酰氧基-1，3-十二碳二烯（11）。
• Novel bisexual attractants, aggregants and arrestants for adults and larvae of codling moth and other species of lepidoptera
  申请人：——

  公开号：US20020061324A1

  公开（公告）日：2002-05-23

  Novel bisexual attractants for lepidopterous insect pests isolated from pears or apples. A method for monitoring and control of codling moth and other species of Lepidoptera comprising a lure and kill, mating disruption or mass trapping strategy. A method of using a formulation containing the bisexual attractants with or without an insecticide and/or pheromone for control of the insect pests.

  从梨或苹果中分离出的新型双性吸引剂，用于吸引鳞翅目害虫。一种监测和控制苹果蠹和其他鳞翅目物种的方法，包括诱杀、交配干扰或大规模捕捉策略。一种使用含有双性吸引剂的配方（带或不带杀虫剂和/或信息素）来控制害虫的方法。
• Attractant composition containing ethyl 3-methylbutanoate and (E,E)-8-,10-dodecadien-1-ol
  申请人：BASF SE

  公开号：EP2735230A1

  公开（公告）日：2014-05-28

  The present invention relates to a composition for controlling undesired insect infestation comprising (E,E)-8,10-dodecadien-1-ol and ethyl 3-methylbutanoate. The invention further relates to a process for the preparation of said composition and a method for controlling undesired insect infestation with said composition.

  本发明涉及一种用于控制虫害的组合物，该组合物由(E,E)-8,10-十二碳二烯-1-醇和 3-甲基丁酸乙酯组成。本发明还涉及一种制备所述组合物的工艺和一种用所述组合物控制虫害的方法。
• SLOW-RELEASE FORMULATION CONTAINING GEL COMPOSITION FOR USE ON PESTS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2805615A1

  公开（公告）日：2014-11-26

  Provided is a sustained release preparation comprising an insect pest-targeting gel composition, the preparation being free from leakage or reaction of a volatile substance and being capable of releasing the volatile substance at a constant rate. More specifically, provided is a sustained release preparation comprising a polymer tube and an insect pest-targeting gel composition in the polymer tube, the composition comprising one or more volatile substances and an oil gelling agent, wherein the volatile substances are comprised in an amount of from 70.0 to 99.0% by weight by the insect pest-targeting composition and are released outside of the polymer tube through the polymer tube.

  本发明提供了一种包含害虫靶向凝胶组合物的缓释制剂，该制剂中的挥发性物质不会泄漏或发生反应，并且能够以恒定的速率释放挥发性物质。更具体地说，本发明提供了一种持续释放制剂，包括聚合物管和聚合物管中的害虫靶向凝胶组合物，该组合物包括一种或多种挥发性物质和油胶凝剂，其中挥发性物质的含量为害虫靶向组合物重量的 70.0% 至 99.0%，并通过聚合物管释放到聚合物管外。