[4-(2,6-dimethylmorpholin-4-yl)phenyl]-[9-ethyl-6-(N-hydroxy-C-methylcarbonimidoyl)carbazol-3-yl]methanone

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [4-(2,6-dimethylmorpholin-4-yl)phenyl]-[9-ethyl-6-(N-hydroxy-C-methylcarbonimidoyl)carbazol-3-yl]methanone
• 化学式: C₂₉H₃₁N₃O₃
• 分子量: 469.6
• InChiKey: AYFKRUOTGQZBJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  35
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  67.1
• 氢给体数：
  1
• 氢受体数：
  5

文献信息

• Oxime Ester Photoinitiators
  申请人：Tanabe Junichi

  公开号：US20080096115A1

  公开（公告）日：2008-04-24

  Compounds of the formula (I), wherein R 1 , R 2 and R 10 independently of one another are C 1 -C 20 alkyl, phenyl, C 1 -C 12 alkylphenyl or phenyl-C 1 -C 6 alkyl; R 3 and R 4 independently of one another are hydrogen, C 1 -C 20 alkyl, NR 6 R 7 or SR 8 , provided that at least one of R 3 or R 4 is NR 6 R 7 or SR 8 ; R 5 is hydrogen or C 1 -C 20 alkyl; R 6 and R 7 independently of one another are C 1 -C 20 alkyl, or R 6 and R 7 together with the N-atom to which they are attached form a 5 or 6 membered ring, which optionally is interrupted by O, S or NR 9 and which optionally additionally is substituted by one or more C 1 -C 4 alkyl; R 8 is phenyl, biphenylyl, naphthyl, anthryl or phenanthryl, all of which optionally are substituted by one or more C 1 -C 4 alkyl; and R 9 is hydrogen, C 1 -C 20 alkyl, C 2 -C 4 hydroxyalkyl or phenyl; exhibit an unexpectedly good performance in photopolymerization reactions.

  化合物的公式（I），其中R1、R2和R10彼此独立地是C1-C20烷基、苯基、C1-C12烷基苯基或苯基-C1-C6烷基；R3和R4彼此独立地是氢、C1-C20烷基、NR6R7或SR8，但至少其中之一是NR6R7或SR8；R5是氢或C1-C20烷基；R6和R7彼此独立地是C1-C20烷基，或者R6和R7连同它们所连接的N原子形成一个5或6元环，该环可以被O、S或NR9中的一个或多个打断，也可以被一个或多个C1-C4烷基取代；R8是苯基、联苯基、萘基、蒽基或菲基，它们都可以选择性地被一个或多个C1-C4烷基取代；R9是氢、C1-C20烷基、C2-C4羟基烷基或苯基。这些化合物在光聚合反应中表现出意外的良好性能。
• US7759043B2
  申请人：——

  公开号：US7759043B2

  公开（公告）日：2010-07-20