(Z)-(o-CH3O)C6H4CHNNHC(S)NH2 | 674779-06-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (Z)-(o-CH3O)C6H4CHNNHC(S)NH2
• 英文别名: o-ANISALDEHYDE, 3-THIOSEMICARBAZONE；[(Z)-(2-methoxyphenyl)methylideneamino]thiourea
• CAS: 674779-06-7
• 化学式: C₉H₁₁N₃OS
• 分子量: 209.272
• InChiKey: LHIPHJZPFNPALV-WDZFZDKYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  91.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 (Z)-(o-CH3O)C6H4CHNNHC(S)NH2 以 甲醇 、 水 为溶剂， 以73%的产率得到(((o-CH3O)C6H4CHNNC(S)NH2)PtCl)2
  参考文献：
  名称：

  Preparation and Investegation of the Bonding Mode in the Complexes of Pt(II) with Thiosemicarbazone Ligands

  摘要：

  Three different thiosemicarbazone (TSC) ligands, BTSC, ClTSC, and MeTSC, derived from benzophenone, p-chlorobenzaidehyde, and m-methoxybenzaldehyde, respectively, were complexed with K2PtCl4. The structures of the complexes were determined on the basis of elemental analyses, IR and H-1, N-15, and C-13 NMR spectral studies, which support the formation of square-planer dimeric complexes of the type [LPtCl2PtL], where L is MeTSC and CITSC, which are N,S containing bidentate ligands. The complex prepared with the ligand BTSC is of the type [L2PtCl2] where L acts as a monodendate ligand as confirmed by CHN analyses. X-ray powder analyses show that the complexes are crystalline.

  DOI：

  10.1081/sim-120023484

文献信息

• Preparation and Investegation of the Bonding Mode in the Complexes of Pt(II) with Thiosemicarbazone Ligands
  作者：M. S. Bakkar、M. Yamin Siddiqi、M. S. Monshi

  DOI：10.1081/sim-120023484

  日期：2003.1.8

  Three different thiosemicarbazone (TSC) ligands, BTSC, ClTSC, and MeTSC, derived from benzophenone, p-chlorobenzaidehyde, and m-methoxybenzaldehyde, respectively, were complexed with K2PtCl4. The structures of the complexes were determined on the basis of elemental analyses, IR and H-1, N-15, and C-13 NMR spectral studies, which support the formation of square-planer dimeric complexes of the type [LPtCl2PtL], where L is MeTSC and CITSC, which are N,S containing bidentate ligands. The complex prepared with the ligand BTSC is of the type [L2PtCl2] where L acts as a monodendate ligand as confirmed by CHN analyses. X-ray powder analyses show that the complexes are crystalline.