N,N'-dimethacryloyl 1,3-diaminobenzene | 25256-12-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dimethacryloyl 1,3-diaminobenzene
• 英文别名: 2-Propenamide, N,N'-1,3-phenylenebis[2-methyl-；2-methyl-N-[3-(2-methylprop-2-enoylamino)phenyl]prop-2-enamide
• CAS: 25256-12-6
• 化学式: C₁₄H₁₆N₂O₂
• 分子量: 244.293
• InChiKey: GPZMMHLFZGNTRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  间苯二胺 、 甲基丙烯酸 、 磷酸酐 、 磷酸 生成 N,N'-dimethacryloyl 1,3-diaminobenzene
  参考文献：
  名称：

  MERCHANT J. R.; CHOTHIA D. S., INDIAN J. TECHNOL. , 1975, 13, NO 8, 814-818

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING A RADIOACTIVE TRACER
  申请人：Perollier Céline

  公开号：US20130053607A1

  公开（公告）日：2013-02-28

  A method for preparing a radioactive tracer provided with a radioactive fluorine isotope, including providing a precursor of the radioactive tracer, comprising at least one leaving group completely or partially formed by a labelling entity, wherein said leaving group can be moved by a fluoride ion, providing a molecularly imprinted polymer dedicated to the molecular recognition of at least the aforementioned labelling entity, exposing the precursor to a radioactive fluoride ion source under conditions suitable for movement of the leaving group by a radioactive fluoride ion, placing the mixture resulting from step (iii) in contact with the molecularly imprinted polymer under conditions suitable for the recognition of the labelling entity, and obtaining a solution containing the radioactive tracer provided with a radioactive isotope of fluorine obtained at the end of step (iii).

  一种制备具有放射性氟同位素的放射性示踪剂的方法，包括提供放射性示踪剂的前体，包括至少一个由标记实体完全或部分形成的离去基团，其中所述离去基团可以被氟离子移动，提供专门用于分子识别至少上述标记实体的分子印迹聚合物，将前体置于适宜于通过放射性氟离子移动离去基团的条件下的放射性氟离子源中，将步骤（iii）产生的混合物与分子印迹聚合物接触，在适宜于识别标记实体的条件下，获得含有放射性氟同位素的放射性示踪剂的溶液，该溶液是在步骤（iii）结束时获得的。
• MOLECULARLY IMPRINTED POLYMERS FOR THE RECOGNITION OF GLUTATHIONE GSH, METHODS FOR PREPARING SAME AND USES THEREOF
  申请人：Perollier Celine

  公开号：US20100234565A1

  公开（公告）日：2010-09-16

  The present invention relates to new molecularly imprinted polymers which are suitable for the selective recognition of glutathione GSH and/or of an analog thereof, and in particular which are of use for the treatment of media comprising in particular a mixture of glutathione GSH, and/or of an analog thereof, with GSH adducts.

  本发明涉及新的分子印迹聚合物，适用于选择性识别谷胱甘肽GSH和/或其类似物，特别是用于处理包括谷胱甘肽GSH和/或其类似物与GSH加合物的介质。
• Molecular Fingerprints With Enhanced Identifying Capability, Method for Preparing Same and Use Thereof
  申请人：Bay-Oudh Sami

  公开号：US20090123411A1

  公开（公告）日：2009-05-14

  The invention concerns a method for preparing a molecular fingerprint comprising sites for identifying at least one target molecule, said fingerprint being obtained from at least one master molecule of polymeric type, called master polymer. The invention is characterized in that said master polymer is different from the target molecule(s), and is capable of being eliminated by degradation and/or washing, and that at least 5% in number of monomer units constituting the master polymer are involved in the formation of the sites for identifying the target molecule(s).

  本发明涉及一种制备分子指纹的方法，该指纹包括用于识别至少一种目标分子的位点，该指纹是从至少一种聚合型母体分子，称为母体聚合物中获得的。本发明的特点在于，所述母体聚合物与目标分子不同，并且能够通过降解和/或清洗被消除，而且构成用于识别目标分子的位点的单体单位中至少有5％参与其中。
• PREPARATION OF MOLECULARLY IMPRINTED POLYMERS BY TWO-PHOTON STEREOLITHOGRAPHY
  申请人：Centre National de la Recherche Scientifique (C.N.R.S.)

  公开号：EP3112021A1

  公开（公告）日：2017-01-04

  The present invention relates to a method using two-photon stereolithography for preparing molecularly imprinted polymers, notably 3D-structured molecularly imprinted polymers.

  本发明涉及一种利用双光子立体光刻技术制备分子印迹聚合物，特别是三维结构分子印迹聚合物的方法。
• Molecularly imprinted polymer for selectively trapping odorous molecules
  申请人：L'ORÉAL

  公开号：US10772823B2

  公开（公告）日：2020-09-15

  The invention relates to the use of molecularly imprinted polymer(s) or MIPs, of odorous molecule(s), as deodorant agent in particular for selectively trapping molecules that are the cause of human body odour. More particularly by using MIPs which may be obtained via polymerization, preferably via radical polymerization, of a mixture of: i) optionally one or more polymerization initiator(s); ii) one or more functional monomer(s); iii) one or more crosslinking agent(s); and iv) one or more porogenic solvent(s); it being understood that the polymerization a) or b) is performed in the presence v) of one or more “templates” of target molecule(s) responsible for human body odour. Another subject of the invention concerns a process for preparing MIPs as defined previously, MIPs obtained via this process, and a cosmetic composition comprising at least one MIP as defined previously. Unexpectedly, it appears that the MIPs make it possible to specifically trap precursors of odorous molecules and odorous molecules that may be used in cosmetic formulations, especially those that are the cause of the unpleasant odour of sweat.

  本发明涉及气味分子的分子印迹聚合物或 MIPs 作为除臭剂的用途，特别是用于选择性地捕获导致人体气味的分子。更具体地说，MIPs 可通过以下混合物的聚合（最好是自由基聚合）获得：i) 一种或多种聚合引发剂；ii) 一种或多种功能性单体；iii) 一种或多种交联剂；iv) 一种或多种致孔溶剂。本发明的另一个主题涉及前文定义的 MIP 制备工艺、通过该工艺获得的 MIP 以及包含至少一种前文定义的 MIP 的化妆品组合物。令人意想不到的是，MIPs 似乎可以专门捕获气味分子的前体和可用于化妆品配方的气味分子，特别是那些导致难闻汗味的分子。