Allyl 2-pentylacrylate | 78450-93-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Allyl 2-pentylacrylate
• 英文别名: prop-2-enyl 2-methylideneheptanoate
• CAS: 78450-93-8
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: SNQXUIMWZNNCTR-UHFFFAOYSA-N

物化性质

• 沸点：
  96 °C(Press: 2.00 Torr)
• 密度：
  1.4422 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-methyleneheptanoic acid 在 氯化亚砜 作用下， 生成 Allyl 2-pentylacrylate
  参考文献：
  名称：

  Marshalok, G.A.; Yatchishin, I. I.; Tolopko, D. K., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, # 4, p. 603 - 608

  摘要：

  DOI：

文献信息

• A General Synthetic Method for α-Methylene Compounds by the Palladium-Catalyzed Decarboxylation-Deacetoxylation of Allyl α-Acetoxymethylcarboxylates Substituted by an Electron-Withdrawing Group at α-position
  作者：Jiro Tsuji、Mohammad Nisar、Ichiro Minami

  DOI：10.1246/cl.1987.23

  日期：1987.1.5

  Allyl α-acetoxymethylcarboxylates substituted by ester, amide, nitro, cyano, and sulfonyl groups at α-position undergo smooth palladium-catalyzed decarboxylation-deacetoxylation under mild neutral conditions to afford corresponding α-methylene compounds in high yields.

  α-位被酯、酰胺、硝基、氰基和磺酰基取代的α-乙酰氧基甲基羧酸烯丙酯在温和的中性条件下进行顺利的钯催化脱羧-脱乙酰氧基化，以高产率得到相应的α-亚甲基化合物。
• Propenoic acid derivatives
  申请人：AgrEvo UK Limited

  公开号：EP0517301A1

  公开（公告）日：1992-12-09

  Compounds of formula I wherein X is CH or N; n is 0, 1, 2 or 3; R¹ and R³, which may be the same or different, are alkyl, alkoxy or alkylthio, each of which is optionally substituted, halogen, nitro, cyano, COOR⁴, -NR⁵R⁶, CONR⁵R⁶, COR⁷ or R⁸S(O)q; or R¹ and an adjacent R³ group, or two adjacent R³ groups, together with the carbon atoms to which they are attached can form a 5 to 8 membered ring which can include 1 to 3 heteroatoms and may be substituted; R² is an optionally substituted aliphatic hydrocarbon radical, which may be unsaturated, aryl or heterocyclyl; R⁴ is hydrogen or an ester forming group; R⁵ and R⁶ are the same or different and are hydrogen, optionally substituted alkyl, acyl or aryl, or together with the nitrogen to which they are attached, form a 5 to 7 membered ring which can contain other hetero atoms; R⁷ is hydrogen, optionally substituted alkyl or aryl; R⁸ is optionally substituted alkyl or aryl; and q is 1 or 2, have fungicidal activity as do the intermediates of formula II wherein R⁹ is hydrogen or methyl, and of formula III

  化合物的公式I，其中X是CH或N; n为0、1、2或3; R¹和R³可以相同也可以不同，是烷基、烷氧基或烷硫基，每个基团都可以选择性地被取代，取代基可以是卤素、硝基、氰基、COOR⁴、-NR⁵R⁶、CONR⁵R⁶、COR⁷或R⁸S（O）q; 或者R¹和相邻的R³基团，或者两个相邻的R³基团，与它们连接的碳原子一起可以形成一个5到8个成员环，其中可以包含1到3个杂原子，并且可以被取代; R²是一个可以选择性取代的脂肪族碳氢基团，可以是不饱和的、芳香的或杂环基团; R⁴是氢或酯基形成基团; R⁵和R⁶相同或不同，是氢、可以选择性取代的烷基、酰基或芳基，或者与它们连接的氮一起形成一个5到7个成员环，其中可以含有其他杂原子; R⁷是氢、可以选择性取代的烷基或芳基; R⁸是可以选择性取代的烷基或芳基; q为1或2，具有杀真菌活性，公式II中的中间体在R⁹为氢或甲基的情况下，公式III也具有杀真菌活性。
• CURABLE GEL INKS WITH REDUCED SYNERESIS AND HALO FORMATION
  申请人：Chrétien Michelle N.

  公开号：US20110074895A1

  公开（公告）日：2011-03-31

  This disclosure is generally directed to curable gel inks, such as radiation-curable phase-change inks, and their use in forming images, such as through inkjet printing. More specifically, this disclosure is directed to radiation-curable gel inks, such as ultraviolet-light-curable phase-change inks, that comprise a curable gellant and a curable solid.

  本公开涉及可治愈凝胶墨水，例如辐射可固化相变墨水，以及它们在形成图像方面的应用，例如通过喷墨打印。更具体地，本公开涉及辐射可固化凝胶墨水，例如紫外线可固化相变墨水，其包括可固化胶凝剂和可固化固体。
• Preparation of alkyl 2-aryl acrylates
  申请人：COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION

  公开号：EP0003670A1

  公开（公告）日：1979-08-22

  Alkyl 2-arylacrylates are prepared by reacting formaldehyde with the appropriate arylacetic ester in a polar solvent in the presence of a base.

  2-芳基丙烯酸烷基酯是在极性溶剂中，在碱存在下，通过甲醛与适当的芳基乙酸酯反应制备而成。
• Stable high solids polymer compositions and a method for preparing the same
  申请人：CALGON CORPORATION

  公开号：EP0672705A2

  公开（公告）日：1995-09-20

  Improved, high solids polymer compositions are prepared via the use of an effective amount of an alkyl(meth)acrylate polymer or an alkyl (meth)acrylate/carboxylic acid polymer as a stabilizer against settling/compaction. Thus, in a preferred mode, a polymer composition containing in excess of about 50%, by weight, polymer solids is stabilized against settling/compaction via addition of an effective amount of a lauryl (meth)acrylate or a lauryl (meth)acrylate/acrylic acid polymer.

  通过使用有效量的烷基（甲基）丙烯酸酯聚合物或烷基（甲基）丙烯酸酯/羧酸聚合物作为防止沉降/压实的稳定剂，可制备出改进的高固体聚合物组合物。因此，在一种优选模式中，通过添加有效量的十二烷基（甲基）丙烯酸酯或十二烷基（甲基）丙烯酸酯/丙烯酸聚合物，使聚合物固体含量超过约 50%（按重量计）的聚合物组合物稳定，以防止沉降/压实。