4-Prop-2-enoyloxycyclohexane-1-carboxylic acid | 1378808-36-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-Prop-2-enoyloxycyclohexane-1-carboxylic acid
• CAS: 1378808-36-6
• 化学式: C₁₀H₁₄O₄
• 分子量: 198.219
• InChiKey: KIGNMHXYUIBIQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-Prop-2-enoyloxycyclohexane-1-carboxylic acid 、 4-[4-(4-Propylphenyl)phenyl]cyclohexan-1-ol 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以48%的产率得到[4-[4-(4-Propylphenyl)phenyl]cyclohexyl] 4-prop-2-enoyloxycyclohexane-1-carboxylate
  参考文献：
  名称：

  POLYMERIZABLE LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION, OPTICAL ANISOTROPIC MATERIAL AND OPTICAL ELEMENT

  摘要：

  公开号：

  EP1760068B1
• 作为产物：
  描述：

  4-羟基环己烷甲酸 、 丙烯酰氯 在 三乙胺 、 盐酸 作用下， 以 四氢呋喃 、 乙醚 、 水 为溶剂， 反应 24.0h， 生成 4-Prop-2-enoyloxycyclohexane-1-carboxylic acid
  参考文献：
  名称：

  POLYMERIZABLE LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION, OPTICAL ANISOTROPIC MATERIAL AND OPTICAL ELEMENT

  摘要：

  公开号：

  EP1760068B1

文献信息

• SALT AND PHOTORESIST COMPOSITION CONTAINING THE SAME
  申请人：Ichikawa Koji

  公开号：US20110014566A1

  公开（公告）日：2011-01-20

  A salt represented by the formula (I-Pa): wherein X pa represents a single bond or a C1-C4 alkylene group, R pa represents a single bond, a C4-C36 divalent alicyclic hydrocarbon group or a C6-C36 divalent aromatic hydrocarbon group, and one or more methylene groups in the divalent alicyclic hydrocarbon group can be replaced by —O— or —CO—, Y pa represents a polymerizable group, and Z pa+ represents an organic cation.

  由公式(I-Pa)表示的盐，其中Xpa代表单一键或C1-C4亚烷基团，Rpa代表单一键、C4-C36二价脂环烃基团或C6-C36二价芳香烃基团，且脂环烃基团中的一个或多个亚甲基基团可以被—O—或—CO—替换，Ypa代表可聚合团，Zpa+代表有机阳离子。
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION, OPTICALLY ANISOTROPIC MATERIAL AND OPTICAL DEVICE
  申请人：Asahi Glass Company, Limited

  公开号：EP1760068A1

  公开（公告）日：2007-03-07

  To provide a novel compound which satisfies characteristics required for an optical anisotropic material and which is excellent in durability against blue laser light, a liquid crystal composition containing the compound, an optical anisotropic material employing the liquid crystal composition and an optical element. A compound represented by the following formula (1):         CH2=CR1-COO- (L)k-E1-E2-E3- (E4)m- (E5)n-R2     (1) provided that the symbols in the formula have the following meanings: R1: a hydrogen atom or a methyl group; R2: a C1-8 alkyl group; L: (CH2)pO-, -(CH2)q-, -Cy-COO- (Cy is a trans-1,4-cyclohexylene group), -Cy-OCO-, -E6-(CH2)2-, -E7-CH2O- or -E8-O- (wherein each of p and q which are independent of each other, is an integer of from 2 to 8); E1, E2, E3, E4, E5, E6, E7, E8,: each independently a 1,4-pheneylene group or a trans-1,4-cyclohexylene group (provided that at least one of E1, E2 and E3 is a trans-1,4-cyclohexylene group, and in a case where L is -Cy-OCO-, E1 is a trans-1,4-cyclohexylene group), provided that the above 1,4-phenylene group and trans-1,4-cyclohexylene group may be such that a hydrogen atom bonded to a carbon atom in each group may be substituted by a fluorine atom, a chlorine atom or a methyl group; and k, m, n: each independently 0 or 1, provided that when k is 1 and L is -Cy-COO-, -Cy-OCO-, -E6-(CH2)2-, -E7-CH2O- or -E8-O-, at least one of m and n is 0.

  提供一种满足光学各向异性材料所需特性且对蓝色激光具有良好耐久性的新型化合物、一种含有该化合物的液晶组合物、一种采用该液晶组合物的光学各向异性材料和一种光学元件。 由下式(1)表示的化合物： CH2=CR1-COO- (L)k-E1-E2-E3- (E4)m- (E5)n-R2 (1) 但式中符号的含义如下： R1：氢原子或甲基； R2：C1-8 烷基； L：(CH2)pO-、-(CH2)q-、-Cy-COO-（Cy 为反式-1,4-环己烯基团）、-Cy-OCO-、-E6-(CH2)2-、-E7-CH2O- 或-E8-O-（其中 p 和 q 互不相关，均为 2 至 8 的整数）； E1, E2, E3, E4, E5, E6, E7, E8,：各自独立的 1，4-烯烃基团或反式-1，4-环己烯基团（条件是 E1、E2 和 E3 中至少有一个是反式-1，4-环己烯基团，在 L 为-Cy-OCO-的情况下，E1 是反式-1，4-环己烯基团）、但上述 1,4-亚苯基基团和反式-1,4-环己烯基团中与每个基团中碳原子结合的氢原子可被氟原子、氯原子或甲基取代；以及 k、m、n：各自独立地为 0 或 1，条件是当 k 为 1 且 L 为-Cy-COO-、-Cy-OCO-、-E6-(CH2)2-、-E7-CH2O-或-E8-O-时，m 和 n 中至少有一个为 0。
• POLYMER, CROSSLINKED POLYMER, COMPOSITION FOR SOLID POLYMER ELECTROLYTE, SOLID POLYMER ELECTROLYTE AND ADHESIVE COMPOSITION
  申请人：NIPPON SODA CO., LTD.

  公开号：EP1847556A1

  公开（公告）日：2007-10-24

  A polymer including a block chain A which is formed from a random copolymer containing a repeating unit (I) represented by the formula (I) wherein R1 to R3 each independently represents hydrogen or C1-10 hydrocarbon and R1 and R3 may bond to form a ring; R4a and R4b each independently represents hydrogen or methyl; R5 represents hydrogen, hydrocarbon, acyl, or silyl; and m represents any integer of 1 to 100 and when m is 2 or more and each R4a may be the same or different from one another and each R4b may be the same or different from one another; and a repeating unit (II) represented by the formula (II) wherein R6 and R8 each independently represents hydrogen or C1-10 hydrocarbon and R6 and R8 may bond to form a ring; R7 represents hydrogen, C1-10 hydrocarbon, hydroxyl, hydrocarbonoxy, carboxyl, acid anhydride, amino, ester, or an organic group having at least one functional group selected from the group consisting of hydroxyl, carboxyl, epoxy, acid anhydride, and amino; and R9 represents an organic group having at least one functional group selected from the group consisting of hydroxyl, carboxyl, epoxy, acid anhydride, and amino; and a block chain B having a repeating unit (III) represented by the formula (III) wherein R10 to R12 each independently represents hydrogen or C1-10 hydrocarbon and R13 represents aryl or heteroaryl; and wherein an arrangement order thereof is B, A, B.

  一种聚合物，包括由无规共聚物形成的嵌段链 A，该共聚物含有由式 (I) 表示的重复单元 (I) 其中 R1 至 R3 各自独立地代表氢或 C1-10 碳氢化合物，R1 和 R3 可键合成环；R4a 和 R4b 各自独立地代表氢或甲基；R5 代表氢、碳氢化合物、酰基或硅基；m 代表 1 至 100 的任意整数，当 m 为 2 或更多时，每个 R4a 可彼此相同或不同，每个 R4b 可彼此相同或不同；以及由式（II）代表的重复单元（II）。 其中 R6 和 R8 各自独立地代表氢或 C1-10 烃，且 R6 和 R8 可键合成环；R7 代表氢、C1-10 烃、羟基、烃氧基、羧基、酸酐、氨基、酯或具有至少一个选自羟基、羧基、环氧基、酸酐和氨基的官能团的有机基团；和 R9 代表具有至少一个选自由羟基、羧基、环氧基、酸酐和氨基组成的组的官能团的有机基团；和 具有由式（III）表示的重复单元（III）的嵌段链 B 其中 R10 至 R12 各自独立地代表氢或 C1-10 烃，R13 代表芳基或杂芳基；以及 其中的排列顺序为 B、A、B。
• Blockcopolymer solid electrolyte, ion-conductive membrane and process for producing the blockcopolymer
  申请人：Nippon Soda Co., Ltd.

  公开号：EP2341510B1

  公开（公告）日：2012-10-31
• Composition for polymer solid electrolyte, polmer solid electrolyte, polymer, polymer solid electrolyte battery, ionconductive membrane, copolymer and process for producing the copolymer
  申请人：Muramoto Hiroo

  公开号：US20070040145A1

  公开（公告）日：2007-02-22

  The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R 1 to R 3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R 4a and R 4b independently represents a hydrogen atom or a methyl group; R 5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R 6 and R 8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R 9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.