1,3-docosanediol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,3-docosanediol
• 英文别名: Docosane-1,3-diol
• 化学式: C₂₂H₄₆O₂
• 分子量: 342.606
• InChiKey: KZKOEECJTCKILD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  24
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2,2-三氟-N,N-二(三甲硅基)乙酰胺 、 1,3-docosanediol 在 吡啶 作用下， 反应 0.5h， 生成
  参考文献：
  名称：

  Homologous long-chain alkanediols from Papaver leaf cuticular waxes

  摘要：

  In cuticular waxes from leaves of Papaver alpinum sensu Markgr., P. dubium L., P. nudicaule L., P. orientale L., P. rhoeas L. and P. somniferum L., six new alkanediols carrying one primary and one secondary hydroxyl function were identified. Five of them, docosane-1,3-diol, hexacosane-1,7-diol, octacosane-1,9-diol, nonacosane-1,10-diol and triacontane-1,11-diol, form a homologous series. Their molecular geometries and relative proportions suggest a biosynthetic relationship to the corresponding primary alkanols.

  DOI：

  10.1016/0031-9422(96)00180-x

文献信息

• Homologous long-chain alkanediols from Papaver leaf cuticular waxes
  作者：Reinhard Jetter、Markus Riederer、André Seyer、Charles Mioskowski

  DOI：10.1016/0031-9422(96)00180-x

  日期：1996.8

  In cuticular waxes from leaves of Papaver alpinum sensu Markgr., P. dubium L., P. nudicaule L., P. orientale L., P. rhoeas L. and P. somniferum L., six new alkanediols carrying one primary and one secondary hydroxyl function were identified. Five of them, docosane-1,3-diol, hexacosane-1,7-diol, octacosane-1,9-diol, nonacosane-1,10-diol and triacontane-1,11-diol, form a homologous series. Their molecular geometries and relative proportions suggest a biosynthetic relationship to the corresponding primary alkanols.