{[bis(1H-indol-3-yl)](1-pyrenyl)}methane | 1016883-56-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: {[bis(1H-indol-3-yl)](1-pyrenyl)}methane
• 英文别名: 3-[1H-indol-3-yl(pyren-1-yl)methyl]-1H-indole
• CAS: 1016883-56-9
• 化学式: C₃₃H₂₂N₂
• 分子量: 446.551
• InChiKey: XOIBGTHKALRBOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  35
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  31.6
• 氢给体数：
  2
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  吲哚 、 1-芘甲醛 在 potassium hydrogensulfate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以95%的产率得到{[bis(1H-indol-3-yl)](1-pyrenyl)}methane
  参考文献：
  名称：

  Bis(indolyl)methane derivatives as highly selective colourimetric and ratiometric fluorescent molecular chemosensors for Cu2+ cations

  摘要：

  New probes based on bis(indolyl)methane derivatives only sense Cu2+ among other heavy and transition metal (HTM) ions through two different channels: the colourless to orange or purple colour change, that is visible to the naked eye, and a remarkable enhancement of the fluorescence along with a large red-shift in emission, in a water containing medium (CH3CN/H2O). (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.12.025

文献信息

• Micro-Cu₄I₄-MOF: reversible iodine adsorption and catalytic properties for tandem reaction of Friedel–Crafts alkylation of indoles with acetals
  作者：Neng-Xiu Zhu、Chao-Wei Zhao、Jian-Cheng Wang、Yan-An Li、Yu-Bin Dong

  DOI：10.1039/c6cc07027b

  日期：——

  We report a convenient approach, the first of kind, to construct microscale non-metal@MOF composite catalystic host-guest system for organic tandem reaction. The reported porous Cu4I4-MOF is able to reversibly adsorb...

  我们报道了一种方便的方法，这是第一种，用于构建有机串联反应的微型非金属@MOF复合催化剂主客体系统。报道的多孔Cu4I4-MOF能够可逆地吸附...
• Bis(indolyl)methane derivatives as highly selective colourimetric and ratiometric fluorescent molecular chemosensors for Cu2+ cations
  作者：Rosario Martínez、Arturo Espinosa、Alberto Tárraga、Pedro Molina

  DOI：10.1016/j.tet.2007.12.025

  日期：2008.2

  New probes based on bis(indolyl)methane derivatives only sense Cu2+ among other heavy and transition metal (HTM) ions through two different channels: the colourless to orange or purple colour change, that is visible to the naked eye, and a remarkable enhancement of the fluorescence along with a large red-shift in emission, in a water containing medium (CH3CN/H2O). (C) 2007 Elsevier Ltd. All rights reserved.