5,7-二甲基金刚烷-1,3-二羧酸 | 13928-68-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 5,7-二甲基金刚烷-1,3-二羧酸
• 中文别名: 5,7-二甲基金刚烷-1,3-二甲酸
• 英文名称: 5,7-dimethyl-1,3-adamantanedicarboxylic acid
• 英文别名: 5,7-dimethyladamantane-1,3-dicarboxylic acid；1,3-Me2-5,7-Ad(COOH)2；5,7-dimethyl-1,3-adamantane dicarboxylic acid；1,3-dimethyladamantane-5,7-dicarboxylic acid；1.3-Dimethyladamantan-5.7-dicarbonsaeure
• CAS: 13928-68-2
• 化学式: C₁₄H₂₀O₄
• mdl: MFCD01825788
• 分子量: 252.31
• InChiKey: KGFHKUZOSKDAKW-UHFFFAOYSA-N

物化性质

• 熔点：
  273-274℃ (acetic acid )
• 沸点：
  371.4±15.0 °C(Predicted)
• 密度：
  1.379±0.06 g/cm3 (20 ºC 760 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 危险等级：
  IRRITANT
• 海关编码：
  2917209090

反应信息

• 作为反应物：
  描述：

  5,7-二甲基金刚烷-1,3-二羧酸 在 manganese(IV) oxide 、 硫酸 作用下， 以56%的产率得到1,3-二羟基-5,7-二甲基金刚烷
  参考文献：
  名称：

  Synthesis of hydroxy derivatives from adamantanecarboxylic acids in the system MnO2–H2SO4

  摘要：

  A convenient procedure has been developed for the synthesis of mono- and dihydric cage alcohols from adamantanecarboxylic acids and their esters using the MnO2-H2SO4 system. The reaction at elevated temperature involved both decarboxylation and decarbonylation of the initial acid or ester.

  DOI：

  10.1134/s1070428016060051
• 作为产物：
  描述：

  甲酸 、 3,5-二甲基-1,7-二溴金刚烷 在 硫酸 作用下， 生成 5,7-二甲基金刚烷-1,3-二羧酸
  参考文献：
  名称：

  Synthesis of perfluoroalkyladamantanes

  摘要：

  DOI：

  10.1021/jo00420a019

文献信息

• Cyclic hydrocarbon perfluorination process
  申请人：Suntech, Inc.

  公开号：US04220606A1

  公开（公告）日：1980-09-02

  Perfluorinated polycyclic hydrocarbons may be produced in high yield by a three-stage process comprising contacting a cyclic hydrocarbon such as an alkyladamantane with a fluoride of silver, manganese, sulfur or the like under varying reaction conditions, generally in the liquid state, to provide a partially fluorinated cyclic hydrocarbon. This fluorination is followed by a second stage vapor phase reaction with a fluoride of cobalt or the like at temperatures generally just above the boiling point of the material to yield highly fluorinated cyclic compounds, followed by a third stage reaction with the same reagent at substantially higher temperatures to provide the desired perfluorinated material. Alternatively, the partially fluorinated material for use in the second stage may be derived from known sources, using any known partially fluorinated cyclic hydrocarbon. In a further embodiment, a fluidized bed reactor may be substituted for the second and third vapor phase stages described above.

  全氟多环碳氢化合物可以通过一个三阶段过程高产率生产，包括将环烃如烷基金刚烷与银、锰、硫等的氟化物在不同反应条件下接触，通常处于液态状态，以提供部分氟化的环烃。这种氟化随后通过第二阶段的气相反应，使用钴等的氟化物，在通常略高于材料的沸点的温度下产生高度氟化的环状化合物，然后通过第三阶段的反应，使用相同的试剂在显著更高的温度下提供所需的全氟化材料。或者，用于第二阶段的部分氟化材料可以源自已知来源，使用任何已知的部分氟化环烃。在另一实施方案中，可以用流化床反应器替代上述第二和第三气相阶段。
• The first selective one-pot synthesis of 1,3-dicarbonyl adamantanes from adamantane and 1,3-dimethyladamantane
  作者：Irena S. Akhrem、Dzhul’etta V. Avetisyan、Luidmila V. Afanas’eva

  DOI：10.1016/j.tetlet.2012.04.125

  日期：2012.7

  A new approach to a simple one-pot functionalization of adamantane and 1,3-dimethyladamantane with CO and various nucleophiles in the presence of the superelectrophilic complex, CBr4·2AlBr3 provides access to important 1,3-dicarbonyl adamantanes with two new functional groups at the bridge-head positions.

  在超亲电子配合物存在下，用一氧化碳和各种亲核试剂将金刚烷和1,3-二甲基金刚烷简单地一锅功能化的新方法，CBr 4 ·2AlBr 3提供了获得具有两个新功能的重要1,3-二羰基金刚烷烷的途径。组在桥头位置。
• Functional norbornanyl ester derivatives, polymers and process for preparing same
  申请人：Yu Hui

  公开号：US20130317156A1

  公开（公告）日：2013-11-28

  This invention relates to the new functional norbornanyl ester derivative and/or polymer compositions which are easily obtainable by reacting the Diels-Alder adduct of appropriate dienes and dienophiles with carboxylic acids. In particular, this invention relates to a new process for making cyclic chemical raw materials suitable for production coating, ink, adhesive, plasticizer, thermoplastic or thermosetting plastic and functional polymers.

  本发明涉及一种新的功能性诺博南酯衍生物和/或聚合物组合物，该组合物通过将适当的二烯和二烯丙基与羧酸反应得到。特别是，本发明涉及一种新的制备环状化学原料的方法，适用于生产涂料、油墨、粘合剂、增塑剂、热塑性或热固性塑料和功能性聚合物。
• Resin Composition, Varnish, Resin Film and Semiconductor Device
  申请人：Enoki Takashi

  公开号：US20090214860A1

  公开（公告）日：2009-08-27

  Disclosed is a resin composition comprising a benzoxazole resin precursor having a first repeating unit obtained by reacting a bisaminophenol compound and a dicarboxylic acid compound, and a cross-linking agent wherein at least one of the bisaminophenol compound and the dicarboxylic acid compound has a diamondoid structure. The benzoxazole resin precursor further comprises a second repeating unit obtained by reacting a bisaminophenol compound not having a diamondoid structure and a dicarboxylic acid compound not having a diamondoid structure. Also disclosed is a resin film comprising the resin composition.

  本发明公开了一种树脂组合物，包括一种苯并噁唑树脂前体，其具有通过反应双氨基酚化合物和二羧酸化合物得到的第一重复单元，以及交联剂，其中双氨基酚化合物和/或二羧酸化合物中至少有一个具有金刚烷结构。苯并噁唑树脂前体还包括通过反应不具有金刚烷结构的双氨基酚化合物和不具有金刚烷结构的二羧酸化合物得到的第二重复单元。此外，本发明还公开了一种包括该树脂组合物的树脂膜。
• Polymerizable silica sol, adamantane derivative for use in the sol and cured resin prepared using the same
  申请人：KAWASAKI STEEL CORPORATION

  公开号：EP0460560A2

  公开（公告）日：1991-12-11

  This invention provides polymerizable silica sols in which at least one monomer containing double bond is used as its dispersion medium, especially a silica sol in which the monomer containing double bond is a monomer containing double bond and OH group or is a monomer having an adamantane structure. This invention also provides compositions which comprise these silica sols as composing elements, cured resins that are obtained by polymerizing these silica sols alone or together with other copolymerizable components, and new adamantane derivatives for use in these silica sols.

  本发明提供了可聚合硅溶胶，其中至少使用了一种含双键的单体作为其分散介质，特别是一种硅溶胶，其中含双键的单体是含双键和 OH 基团的单体或具有金刚烷结构的单体。本发明还提供了以这些硅溶胶为组成元素的组合物、通过单独聚合这些硅溶胶或与其他可共聚组分一起聚合而得到的固化树脂，以及用于这些硅溶胶的新金刚烷衍生物。