N,N'-4,4'-Diphenylmethan-bis-citraconimid | 47619-10-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-4,4'-Diphenylmethan-bis-citraconimid
• 英文别名: 1,1'-[Methylenedi(4,1-phenylene)]bis(3-methyl-1H-pyrrole-2,5-dione)；3-methyl-1-[4-[[4-(3-methyl-2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione
• CAS: 47619-10-3
• 化学式: C₂₃H₁₈N₂O₄
• 分子量: 386.407
• InChiKey: JOIKTXAWXLKFFD-UHFFFAOYSA-N

物化性质

• 沸点：
  591.0±43.0 °C(Predicted)
• 密度：
  1.348±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  柠康酸酐 、 4,4'-二氨基二苯甲烷 在 magnesium acetate 、 乙酸酐 、 三乙胺 作用下， 以 丙酮 为溶剂， 生成 N,N'-4,4'-Diphenylmethan-bis-citraconimid
  参考文献：
  名称：

  Gaina, Viorica; Gaina, Constantin, Revue Roumaine de Chimie, 2010, vol. 55, # 10, p. 647 - 652

  摘要：

  DOI：

文献信息

• Heat-resistant thermosetting resin composition
  申请人：KABUSHIKI KAISHA TOSHIBA

  公开号：EP0031904A1

  公开（公告）日：1981-07-15

  A thermosetting resin composition containing as essential resin components (a) a maleimide compound modified with furfuryl alcohol, (b) an epoxy resin and (c) a polyvinyl formal, and a latent curing agent or a curing accelerator which is at least one compound selected from the group consisting of dicyandiamide, boron trifluoride-amine complexes, metal chelate compounds, and silicone compounds and organo- silane compounds having at least one hydroxyl group bonded directly to silicon atom, is found to be capable of B-staging with good storage stability and provides a heat-resistant resin composition having excellent electric characteristics at high temperatures after curing. The composition can suitably be : coated on a glass cloth or a mica tape to give a pre-preg tape which can maintain its flexibility for a long time.

  一种热固性树脂组合物含有以下树脂基本成分：(a)用糠醇改性的马来酰亚胺化合物，(b)环氧树脂和(c)聚乙烯正式，以及一种潜伏固化剂或固化促进剂，该固化剂或固化促进剂至少是一种选自由双氰胺、三氟化硼-胺络合物、金属螯合物、硅化合物和至少有一个羟基直接与硅原子键合的有机硅烷化合物组成的组中的化合物、该固化剂或固化促进剂至少是一种选自双氰胺、三氟化硼胺络合物、金属螯合物、硅化合物和至少有一个羟基直接与硅原子键合的有机硅烷化合物的化合物。这种组合物可以适当地涂在玻璃布或云母带上，以得到一种能长期保持柔韧性的预浸带。
• Photo-curable epoxy resin type composition and curing process
  申请人：KABUSHIKI KAISHA TOSHIBA

  公开号：EP0195846A2

  公开（公告）日：1986-10-01

  A photo-curable epoxy resin type composition which comprises (a) an epoxy resin, (b) a compound having at least one group represented by the formula: -NH-, (c) an organic metal compound, and (d) an organic silicon compound capable of forming a silanol group by irradiation with light. The photo-curable epoxy resin type composition according to this invention is capable of readily curing by light (ultraviolet ray in particular) and also capable of heat-curing at a temperature of 150 °C or more, and yet free from inclusion of ionic impurities from the cured product, free from corrosion of metallic materials which may be in contact with the composition, and having excellent electrical properties.

  一种光固化环氧树脂型组合物，它包括：(a) 环氧树脂；(b) 具有至少一个由式-NH-表示的基团的化合物；(c) 有机金属化合物；(d) 通过光照射能形成硅烷醇基的有机硅化合物：-NH-；(c) 有机金属化合物；(d) 有机硅化合物，通过光照射可形成硅醇基。根据本发明的光固化环氧树脂型组合物能够通过光（特别是紫外线）轻易固化，也能在 150 °C 或更高温度下加热固化，但固化产物中不含有离子杂质，不会腐蚀可能与组合物接触的金属材料，并具有优异的电气性能。
• Process for the preparation of heterocyclic styryl compounds and reaction products
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0240011A2

  公开（公告）日：1987-10-07

  Heterocyclic compounds having the formula where R is hydrogen. methyl or ethyl R, independently in each occurrence is hydrogen, alkyl group of 1-4 carbons, and -C(R):CH-Q n is a number having an average value from 0 to 5 Q has the formula Z is = 0, = S, or = N-R2 R is selected from hydrogen, alkyl, aryl, alkaryl, and aralkyl is a monocyclic or bicyclic heterocyclic ring selected from the group consisting of pyridine, pyrazine, pyridazine, pyrimidine, quinoline, isoquinoline, quinoxaline, quinazoline and phthalazine x is 1 to 3 with the proviso that when n is zero, the heterocyclic ring has at least two -C(R):CH-Q groups are prepared by condensing nitrogen heterocyclic compounds such as trimethyl pyridine with dialdehydes and heterocyclic aldehydes such as furfural. These can be further reacted and chain extended with bismaleimides or polymaleimides. The compounds and their reaction products are useful to make heat resistant composites with various fibers such as graphite fibers.

  具有以下式子的杂环化合物 其中 R 为氢、甲基或乙基 每次独立出现的 R 分别为氢、1-4 个碳原子的烷基和-C(R):CH-Q n 是一个平均值为 0 至 5 的数字 Q 的式子为 Z 是＝0、＝S 或＝N-R2 R 选自氢、烷基、芳基、烷芳基和芳烷基 是单环或双环杂环，选自由吡啶、吡嗪、哒嗪、嘧啶、喹啉、异喹啉、喹喔啉、喹唑啉和酞嗪组成的组 x 为 1 至 3 但当 n 为零时，杂环至少有两个 -C(R):CH-Q 基团 通过将含氮杂环化合物（如三甲基吡啶）与二醛和杂环醛（如糠醛）缩合制备。这些化合物可与双马来酰亚胺或聚马来酰亚胺进一步反应和扩链。这些化合物及其反应产物可与各种纤维（如石墨纤维）制成耐热复合材料。
• Thermosettable resin compositions
  申请人：HERCULES INCORPORATED

  公开号：EP0304009A1

  公开（公告）日：1989-02-22

  Disclosed are a reaction mixture for preparing a poly­functional maleimide-based thermosettable resin composition comprising a bismaleimide or a polymaleimide and an ether derivative of an alkenylphenol; the polyfunctional maleimide-­based thermosettable resins comprising the reaction product of the reaction mixture; a process for the manufacture of the resins; and their use in a prepreg containing carbon, boron. glass or other fibers.

  公开了一种用于制备多官能团马来酰亚胺基热沉性树脂组合物的反应混合物，该组合物包括双马来酰亚胺或聚马来酰亚胺和烯基苯酚的醚衍生物；多官能团马来酰亚胺基热沉性树脂包括反应混合物的反应产物；树脂的制造工艺；以及它们在含有碳、硼、玻璃或其他纤维的预浸料中的用途。
• Heat resistant thermosetting phosphazene-imide copolymers
  申请人：HERCULES INCORPORATED

  公开号：EP0313863A2

  公开（公告）日：1989-05-03

  Novel thermoset polymers are prepared by reacting an allyl or vinyl aryl or aryloxy substituted cyclophosphazene with a bis-maleimide.

  新型热固性聚合物是由烯丙基或乙烯基芳基或芳基氧基取代的环磷炯与双马来酰亚胺反应制备而成。