7-bromo-3-bromomethyl-2,3,6-trichloro-7-methyl-oct-1-ene | 58086-79-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 7-bromo-3-bromomethyl-2,3,6-trichloro-7-methyl-oct-1-ene
• 英文别名: 7-Bromo-3-(bromomethyl)-2,3,6-trichloro-7-methyloct-1-ene
• CAS: 58086-79-6
• 化学式: C₁₀H₁₅Br₂Cl₃
• 分子量: 401.396
• InChiKey: ZFHCZRDDIPJYNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  7-bromo-3-bromomethyl-2,3,6-trichloro-7-methyl-oct-1-ene 在 chromium sulfate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-(4-bromo-3-chloro-4-methyl-pentyl)-3-chloro-buta-1,3-diene
  参考文献：
  名称：

  EVIDENCE FOR THE BIOGENESIS OF HALOGENATED MYRCENES FROM THE RED ALGACHONDROCOCCUS HORNEMANNI

  摘要：

  Several new halogenated monoterpenes (3–6,10–15) have been isolated from Hawaiian Chondrococcus hornemanni which suggest that the halogenated myrcenes are formed by the enzymatic addition of BrCl followed by dehydrohalogenation.

  DOI：

  10.1246/cl.1975.1111

文献信息

• EVIDENCE FOR THE BIOGENESIS OF HALOGENATED MYRCENES FROM THE RED ALGA<i>CHONDROCOCCUS HORNEMANNI</i>
  作者：B. Jay Burreson、Frank X. Woolard、Richard E. Moore

  DOI：10.1246/cl.1975.1111

  日期：1975.11.5

  Several new halogenated monoterpenes (3–6,10–15) have been isolated from Hawaiian Chondrococcus hornemanni which suggest that the halogenated myrcenes are formed by the enzymatic addition of BrCl followed by dehydrohalogenation.