10-Methoxy-[9]anthrol | 189502-14-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 10-Methoxy-[9]anthrol
• 英文别名: 10-Methoxyanthracen-9-ol
• CAS: 189502-14-5
• 化学式: C₁₅H₁₂O₂
• 分子量: 224.259
• InChiKey: HEEPFNCXCOLFGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  蒽醌 在 sodium hydroxide 、 锌 作用下， 生成 10-Methoxy-[9]anthrol
  参考文献：
  名称：

  Meyer,K. H., Justus Liebigs Annalen der Chemie, 1911, vol. 379, p. 70

  摘要：

  DOI：

文献信息

• HETEROZYKLISCHE SELENA-PHOSPHITE SOWIE VERFAHREN ZU DEREN HERSTELLUNG
  申请人：Evonik Degussa GmbH

  公开号：EP3178828A1

  公开（公告）日：2017-06-14

  Neue heterozyklische Selena-Phosphite, Verfahren zu deren Herstellung als auch deren Verwendung als Liganden für eine Anwendung in Komplexen.

  新型杂环硒磷酸盐、其制备过程以及作为配体在络合物中的应用。
• Sodium Bis(trimethylsilyl)amide and Lithium Diisopropylamide in Deprotection of Alkyl Aryl Ethers:  α-Effect of Silicon
  作者：Jih Ru Hwu、Fung Fuh Wong、Jiann-Jyh Huang、Shwu-Chen Tsay

  DOI：10.1021/jo961191k

  日期：1997.6.13

  Removal of methyl, benzyl, and methylene groups from alkyl aryl ethers is among the most popular deprotecting methods in organic synthesis. Alkali organoamides NaN(SiMe3)(2) and LiN(i-Pr)(2), often used as organic bases, have been developed as efficient deprotecting agents. Treatment of aryl methyl ethers with 1.5 equiv of NaN(SiMe3)(2) or LiN(i-Pr)(2) in THF and 1,3-dimethyl-2-imidazolidinone in a sealed tube at 185 degrees C produced the corresponding phenol derivatives in good to excellent yields (80-97%). Removal of the methylene unit from benzodioxole derivatives was also accomplished by use of 2.5 equiv of these alkali organoamides. The corresponding catechols were obtained in 93-99% yields. The activity of NaN(SiMe3)(2) was proven lower than that of LiN(i-Pr)(2); it is due to the steric congestion and the alpha-stabilizing effect of the silyl groups. Thus selective mono-O-demethylation of o-dimethoxybenzenes can be achieved by the use of NaN(SiMe3)(2) but not LiN(i-Pr)(2). O-Debenzylation of aryl benzyl ethers, however, can be accomplished by the use of LiN(i-Pr)(2).
• Woroshzow; Aleksandrow, Zhurnal Obshchei Khimii, 1940, vol. 10, p. 869,877,878
  作者：Woroshzow、Aleksandrow

  DOI：——

  日期：——
• [EN] HINDERED AMINE STABILIZED UV ACTIVE ORGANOPALLADIUM CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS<br/>[FR] COMPOSITIONS DE POLYCYCLOOLÉFINE CATALYSÉES PAR ORGANOPALLADIUM ACTIVES AUX UV STABILISÉES PAR AMINE ENCOMBRÉE EN TANT QUE MATÉRIAUX OPTIQUES
  申请人：PROMERUS LLC

  公开号：WO2021262921A1

  公开（公告）日：2021-12-30

  Embodiments in accordance with the present invention encompass compositions comprising a organopalladium compound, a photoacid generator, a photosensitizer, one or more olefinic monomers and a stabilizer, such as for example a hindered amine, which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The compositions of this invention are stable at room temperature for several days to several months and can also be stored at higher temperatures from about 40 °C to 60° C for several days and undergo mass polymerization only when subjected to suitable actinic radiation. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, sealants, adhesives, among others.
• Meyer,K. H., Justus Liebigs Annalen der Chemie, 1911, vol. 379, p. 70
  作者：Meyer,K. H.

  DOI：——

  日期：——