bis(4-chlorobutyl) hexanedioate | 67803-71-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: bis(4-chlorobutyl) hexanedioate
• 英文别名: adipic acid bis-(4-chloro-butyl ester)；Adipinsaeure-bis-(4-chlor-butylester)
• CAS: 67803-71-8
• 化学式: C₁₄H₂₄Cl₂O₄
• 分子量: 327.248
• InChiKey: CHBMJHWVAIPKBW-UHFFFAOYSA-N

物化性质

• 沸点：
  225-227 °C(Press: 2 Torr)
• 密度：
  1.130±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  己二酸 在 四氢呋喃 、 盐酸 、 zinc(II) chloride 作用下， 生成 bis(4-chlorobutyl) hexanedioate
  参考文献：
  名称：

  DE725528

  摘要：

  公开号：

文献信息

• Palladium(II) acetate catalyzed acylative cleavage of cyclic and acyclic ethers under neat conditions
  作者：Jean Fotie、Brandy R. Adolph、Shreya V. Bhatt、Casey C. Grimm

  DOI：10.1016/j.tetlet.2017.10.080

  日期：2017.12

  During the development of a palladium catalyzed C–H activation cross-coupling reaction involving acyl halides, it was noted that palladium(II) acetate catalyzes the acylative cleavage of tetrahydrofuran (used as a solvent) at room temperature to afford the corresponding 4-chlorobutyl ester derivative. After optimization, the reaction was shown to work well with epoxides, oxetane and tetrahydrofuran

  在涉及酰基卤的钯催化的C–H活化交叉偶联反应的开发过程中，注意到乙酸钯（II）在室温下催化四氢呋喃（用作溶剂）的酰化裂解，得到相应的4-氯丁基酯衍生物。优化后，显示该反应在环氧化物，氧杂环丁烷和四氢呋喃中反应良好，但在室温下仅与氧烷勉强反应。无环醚在相似条件下无法系统反应，但在100°C的微波反应器中进行了完全转化。
• Miyakawa; Hagihara, 1957, vol. 10, p. 49
  作者：Miyakawa、Hagihara

  DOI：——

  日期：——
• HIGHLY ELASTIC POLYVINYL CHLORIDE COMPOSITION AND PRODUCTS PREPARED USING THE SAME
  申请人：LG Chem. Ltd.

  公开号：EP1913081A1

  公开（公告）日：2008-04-23
• Highly elastic polyvinyl chloride composition and products prepared using the same
  申请人：Joo Munkyu

  公开号：US20070037929A1

  公开（公告）日：2007-02-15

  A highly elastic polyvinyl chloride composition comprises polyvinyl chloride-rubber particles including rubber particles and secondary polyvinyl chloride particles formed by combination of primary polyvinyl chloride particles. In the polyvinyl chloride-rubber particles, pores between primary polyvinyl chloride particles that form secondary polyvinyl chloride particles are filled with rubber particles. A film manufactured using the polyvinyl chloride composition has high elasticity, and rubber particles contained in the film have high uniformity. In addition, by using cross-linked rubber particles, the polyvinyl chloride composition may show high elongation, large tensile strength, and excellent processability due to no increase in viscosity even when the content of plasticizer used is not increased during a film formation process.
• US4094850A
  申请人：——

  公开号：US4094850A

  公开（公告）日：1978-06-13