Pentafluorophenyl phosphorus and arsenic complexes of iron, ruthenium, and molybdenum
作者:M. Cooke、M. Green、D. Kirkpatrick
DOI:10.1039/j19680001507
日期:——
[π-C5H5Mo(CO)3]– affords the mononuclear complexes (C6F5)2EFe(CO)2π-C5H5 and (C6H5)2EMo(CO)3π-C5H5. The arsenic complexes can also be prepared by reaction of [(C6F5)2As]2 with [π-C5H5Fe(CO)2]2 and [π-C5H5Mo(CO)3]2. Attempts to capture (C6F5)2PLi with π-C5H5Fe(CO)2Cl or π-C5H5Mo(CO)3Cl were unsuccessful. U.v. irradiation of the mononuclear arsenic complexes gave [(C6F5)2AsFe(CO)π-C5H5]n and [(C6F5)2AsMO(CO)2π-C5H5]n
(C的治疗6 ˚F 5)2与阴离子[ECL(E = P或As)π -C 5 ħ 5的Fe(CO)2 ] -和[ π -C 5 ħ 5的Mo(CO)3 ] - ,得到单核络合物(C 6 ˚F 5)2 EFE(CO)2 π -C 5 ħ 5和(C 6 H ^ 5)2 EMO(CO)3 π -C 5 ħ 5。砷配合物也可以通过[(C 6 F 5)2 As] 2与[ π- C 5 H 5 Fe(CO)2 ] 2和[ π- C 5 H 5 Mo(CO)3 ]反应制备。2。尝试用π- C 5 H 5 Fe(CO)2 Cl或π- C 5 H 5 Mo(CO)3捕获(C 6 F 5)2 PLiCl不成功。单核砷配合物的UV照射,得到[(C 6 ˚F 5)2 ASFE(CO)π -C 5 ħ 5 ] Ñ和[(C 6 ˚F 5)2 ASMO(CO)2 π -C 5 ħ 5 ] Ñ。[(C 6 F 5)2 E]