1,2,3,4,5,6-Hexachlor-cyclohex-1-en | 1890-41-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,2,3,4,5,6-Hexachlor-cyclohex-1-en
• 英文别名: Hexachlorcyclohexen；β-1,2,3,4,5,6-Hexachlorcyclohexen；α-1,2,3,4,5,6-Hexachlor-cyclohex-1-en；α-1,2,3,4,5,6-Hexachlorcyclohexen；optically inactive 1,2,3,4,5,6-hexachloro-cyclohexene；β-1,2,3,4,5,6-Hexachlor-cyclohex-1-en；Opt.-inakt. 1,2,3,4,5,6-Hexachlor-cyclohexen；1,2,3,4,5,6-Hexachlorocyclohexene
• CAS: 1890-41-1
• 化学式: C₆H₄Cl₆
• 分子量: 288.816
• InChiKey: RTXWYBKYSKCFNF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,3,4,5,6-Hexachlor-cyclohex-1-en 在 氢氧化钾 作用下， 生成 1,2,3,5-四氯苯 、 1,2,3,4-四氯苯
  参考文献：
  名称：

  The Partial Additive Chlorination of the Benzene Ring. III. Pentachlorccyclohexene and Hexachlorocyclohexene

  摘要：

  DOI：

  10.1021/ja01634a012
• 作为产物：
  描述：

  邻二氯苯 在 碘 、 氯 作用下， 生成 1,2,3,4,5,6-Hexachlor-cyclohex-1-en
  参考文献：
  名称：

  The Partial Additive Chlorination of the Benzene Ring. III. Pentachlorccyclohexene and Hexachlorocyclohexene

  摘要：

  DOI：

  10.1021/ja01634a012

文献信息

• DNA shuffling of monooxygenase genes for production of industrial chemicals
  申请人：MAXYGEN, INC.

  公开号：US20030215859A1

  公开（公告）日：2003-11-20

  This invention provides improved monoxygenases, dehydrogenases, and transferases that are useful for the biocatalytic synthesis of compounds such as &agr;-hydroxycarboxylic acids, and aryl- and alkyl-hydroxy compounds. The polypeptides provided herein are improved in properties such as regioselectivity, enzymatic activity, stereospecificity, and the like. Methods for obtaining recombinant polynucleotides that encode these improved polypeptides are also provided, as are organisms that express the polypeptides and are thus useful for carrying out said biocatalytic syntheses. Also provided by the invention are methods for increasing said solvent resistance of organisms that are used in the synthetic methods.

  本发明提供了改进的单加氧酶、脱氢酶和转移酶，可用于生物催化合成α-羟基羧酸和芳基-和烷基-羟基化合物等化合物。本文所提供的多肽在区域选择性、酶活性、立体特异性等性质方面得到了改进。本发明还提供了获得编码这些改进多肽的重组多核苷酸的方法，以及表达这些多肽并因此用于进行上述生物催化合成的有用的生物体。本发明还提供了用于增加用于合成方法的生物体的溶剂耐受性的方法。
• Removal of halogenated organic compounds from organic fluids
  申请人：Calspan Corporation

  公开号：EP0107404A1

  公开（公告）日：1984-05-02

  Organic functional fluids containing halogenated organic compounds present as contaminants therein are treated with a NaPEG decomposition reagent in an inert atmosphere to produce a functional fluid phase substantially free of the halogenated organic compound and a reagent residue phase containing a partially dehalogenated organic derivative therein. The latter may be further dehalogenated by reacting the reagent residue with oxygen.

  在惰性气氛中，用 NaPEG 分解试剂处理含有作为污染物存在的卤代有机化合物的有机功能流体，以产生基本上不含卤代有机化合物的功能流体相和含有部分脱卤有机衍生物的试剂残留物相。后者可通过试剂残留物与氧气反应进一步脱卤。
• DNA SHUFFLING OF MONOOXYGENASE GENES FOR PRODUCTION OF INDUSTRIAL CHEMICALS
  申请人：Maxygen, Inc.

  公开号：EP1104459A1

  公开（公告）日：2001-06-06
• US4053439A
  申请人：——

  公开号：US4053439A

  公开（公告）日：1977-10-11
• US4417977A
  申请人：——

  公开号：US4417977A

  公开（公告）日：1983-11-29