1-Fluoroperylene | 77629-23-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1-Fluoroperylene
• CAS: 77629-23-3
• 化学式: C₂₀H₁₁F
• 分子量: 270.306
• InChiKey: PMDCVRWTHXGWNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-二萘嵌苯胺 生成 1-Fluoroperylene
  参考文献：
  名称：

  Cation radicals. 47. Reaction of perylene cation radical with fluoride ion and of perylene with xenon difluoride. Formation of 1-fluoro-, 3-fluoro-, and a difluoroperylene. Complications with chloride ion impurity

  摘要：

  DOI：

  10.1021/jo00328a035

文献信息

• Method for transferring TCPX into TFPX
  申请人：Lin Chun-Hsu

  公开号：US20060211894A1

  公开（公告）日：2006-09-21

  A method for transferring TCPX (α, α, α′, α′-tetrachloro-p-xylene) into TFPX (α, α, α′, α′-tetrafluoro-p-xylene) is disclosed, which comprises the following steps: (a) providing a first reactant comprising TFPX; (b) mixing the first reactant with alkali metal fluorides, TCPX and phase transfer catalyst(s) to form a mixture, wherein the alkali metal fluorides is KF, CsF, NaF, LiF or the combination thereof, the phase transfer catalyst(s) is quaternary ammonium salt, quaternary phosphonium salt or the combination thereof; and (c) heating the mixture.

  本发明公开了一种将TCPX（α，α，α′，α′-四氯-p-二甲苯）转化为TFPX（α，α，α′，α′-四氟-p-二甲苯）的方法，包括以下步骤：(a)提供含有TFPX的第一反应物；(b)将第一反应物与碱金属氟化物、TCPX和相转移催化剂混合形成混合物，其中碱金属氟化物为KF、CsF、NaF、LiF或其组合，相转移催化剂为季铵盐、季磷盐或其组合；(c)加热混合物。
• Method for synthesizing TFPX
  申请人：Ho Chan-Yuan

  公开号：US20060211895A1

  公开（公告）日：2006-09-21

  A method for the synthesis of TFPX (α,α,α′,α′-tetrafluoro-p-xylene) is disclosed, which comprises the following steps: (a) providing a sulpholane solution comprising TCPX (α,α,α′,α′-tetrachloro-p-xylene); (b) mixing the sulpholane solution with alkali metal fluoride, and phase transfer catalyst to form a mixture, wherein the phase transfer catalyst is quaternary phosphonium salt; and (c) heating the mixture.

  公开了一种合成TFPX（α，α，α′，α′-四氟-p-二甲苯）的方法，包括以下步骤：(a)提供一个含有TCPX（α，α，α′，α′-四氯-p-二甲苯）的硫代乙烷溶液；(b)将硫代乙烷溶液与碱金属氟和相转移催化剂混合形成混合物，其中相转移催化剂是季铵磷盐；(c)加热混合物。
• Organic thin film element
  申请人：KABUSHIKI KAISHA TOSHIBA

  公开号：EP0478380A1

  公开（公告）日：1992-04-01

  An organic thin film element is disclosed which has an organic thin film consisting of a mixed stacked charge-transfer complex of donor and acceptor molecules, wherein the organic thin film is made neutral by forming the mixed stacked charge-transfer complex which is ionic under the bulk state into a thin film.

  本发明公开了一种有机薄膜元件，其有机薄膜由供体分子和受体分子的混合叠层电荷转移络合物组成，其中有机薄膜是通过将体态下呈离子性的混合叠层电荷转移络合物形成薄膜而成为中性的。
• Organic semiconductor formulations
  申请人：Flexterra, Inc.

  公开号：US10043978B2

  公开（公告）日：2018-08-07

  The present teachings relate to organic semiconductor formulations including an organic semiconducting compound in a liquid medium, where the liquid medium includes (1) a compound in liquid state that has electronic properties complementary to the electronic structure of the organic semiconducting compound and optionally (2) a solvent or solvent mixture for solubilizing the organic semiconducting compound. The present formulations can be used as inks in the fabrication of organic semiconductor devices.

  本发明涉及有机半导体制剂，包括液体介质中的有机半导体化合物，其中液体介质包括（1）液态化合物，该化合物具有与有机半导体化合物电子结构互补的电子特性，以及（2）用于溶解有机半导体化合物的溶剂或溶剂混合物。本制剂可用作制造有机半导体器件的油墨。
• Medicament dispenser
  申请人：Taylor James Anthony

  公开号：US20050039743A1

  公开（公告）日：2005-02-24

  There is provided a medicament container or delivery device for use with medicament in dry powder form comprising a material that reduces the surface energy or increases the electrical conductivity of some or all parts of the medicament container or delivery device which come into contact with said dry powder form medicament. Suitably, the material has friction-reducing or electrical conductivity-enhancing properties.

  本发明提供了一种用于干粉状药物的药物容器或给药装置，其中包含一种材料，可降低药物容器或给药装置中与所述干粉状药物接触的部分或全部零件的表面能或提高其导电性。材料最好具有减少摩擦或增强导电性能的特性。