2-Ethenylsulfonylethoxybenzene | 5535-57-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-Ethenylsulfonylethoxybenzene
• CAS: 5535-57-9
• 化学式: C₁₀H₁₂O₃S
• 分子量: 212.269
• InChiKey: QQLBBMXUMAPIEQ-UHFFFAOYSA-N

物化性质

• 熔点：
  84-85 °C
• 沸点：
  396.5±25.0 °C(Predicted)
• 密度：
  1.185±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二乙烯基砜 、 苯酚 在 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 2-Ethenylsulfonylethoxybenzene
  参考文献：
  名称：

  二乙烯基砜的亲核试剂介导的oxa-Michael加成反应-逐步增长聚合反应的无硫醇选项†

  摘要：

  三苯基膦和4-二甲基氨基吡啶促进了醇与二乙烯基砜的氧杂-迈克尔加成反应。在无溶剂条件下，反应特别快，可以制备聚合物。

  DOI：

  10.1039/c5cy01527h

文献信息

• Silicone-sulfone and silicone-fluorocarbon-sulfone gas permeable contact lenses and compositions thereof
  申请人：PROGRESSIVE OPTICAL RESEARCH LTD.

  公开号：EP0231572A2

  公开（公告）日：1987-08-12

  Highly oxygen permeable hard and semi-hard contact lenses are made from the copolymer of ethylenically unsaturated siloxane ester, ethylenically unsaturated fluorocarbon ester and ethylenically unsaturated sulfone monomer and methods for the polymerization thereof.

  高透氧硬性和半硬性隐形眼镜由乙烯不饱和硅氧烷酯、乙烯不饱和碳氟化合物酯和乙烯不饱和砜单体的共聚物及其聚合方法制成。
• Fluorosulfone-silicone hydrogel RGP contact lenses, optical medical devices and compositions thereof
  申请人：Novicky, Nick N.

  公开号：EP1455201A1

  公开（公告）日：2004-09-08

  Highly comfortable oxygen permeable and hydrophilic contact lenses are manufactured from a copolymer of an ethylenically unsaturated novel monomers Bis(perfluoroalkylsulfonyl)-amidoethyl methacrylate, Bis(alkylsulfonyl)amidoethyl methacrylate, (N-alkylsulfonyl-N'-perfluoroalkylsulfonyl)amidoethyl methacrylate and organosilicone ester monomers of acrylic and methacrylic acid and ethylenically unsaturated ester monomers of methacrylic acid having alkyl hydroxy groups, N-vinyl 2-pyrolidinone, dimethylacrylamide, methacrylic acid and methods for the manufacturing thereof.

  高度舒适的透氧性和亲水性隐形眼镜是由乙烯不饱和新型单体甲基丙烯酸双(全氟烷基磺酰基)酰胺乙基酯、甲基丙烯酸双(烷基磺酰基)酰胺乙基酯、甲基丙烯酸(N-烷基磺酰基-N'-全氟烷基磺酰基)酰胺乙基酯和有机硅酯单体的共聚物制成的、(N-烷基磺酰基-N'-全氟烷基磺酰基)氨基甲基丙烯酸乙酯、丙烯酸和甲基丙烯酸的有机硅酯单体以及具有烷基羟基的甲基丙烯酸乙烯基不饱和酯单体、N-乙烯基 2-吡咯烷酮、二甲基丙烯酰胺、甲基丙烯酸及其制造方法。
• Fluorocarbon-sulfone hydrophilic contact lenses, optical medical devices and compositions thereof
  申请人：——

  公开号：US20030027886A1

  公开（公告）日：2003-02-06

  Highly comfortable hydrophilic contact lenses are made from a coploymer of an ethylenically unsaturated fluoro-sulfone ester, ethylenically unsaturated fluorosulfone ester monomer of acrylic or methacrylic acid having alkyl hydroxy group and N-Vinyl 2-pyrrolidinone and methods for the manufacturing thereof.

  高舒适度亲水性隐形眼镜由乙烯不饱和氟砜酯共聚物、具有烷基羟基的丙烯酸或甲基丙烯酸乙烯不饱和氟砜酯单体和 N-乙烯基 2-吡咯烷酮及其制造方法制成。
• Fluorosulfone-silicone hydrogel, RGP contact lenses, optical medical devices and compositions thereof
  申请人：Novicky Nick

  公开号：US20050176907A1

  公开（公告）日：2005-08-11

  Highly comfortable oxygen permeable and hydrophilic contact lenses are manufactured from a copolymer of an ethylenically unsaturated novel monomers Bis(perfluoroalkylsulfonyl)-amidoethyl methacrylate, Bis(alkylsulfonyl)amidoethyl methacrylate, (N-alkylsulfonyl-N′-perfluoroalkylsulfonyl)amidoethyl methacrylate and organosilicone ester monomers of acrylic and methacrylic acid and ethylenically unsaturated ester monomers of methacrylic acid having alkyl hydroxy groups, N-vinyl 2-pyrolidinone, dimethylacrylamide, methacrylic acid and methods for the manufacturing thereof.
• US4748224A
  申请人：——

  公开号：US4748224A

  公开（公告）日：1988-05-31