Methyl-cinnamyl-sulfon | 91061-29-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methyl-cinnamyl-sulfon
• 英文别名: 3-Methylsulfonylprop-1-enylbenzene；3-methylsulfonylprop-1-enylbenzene
• CAS: 91061-29-9
• 化学式: C₁₀H₁₂O₂S
• 分子量: 196.27
• InChiKey: FLZFIKYBSDONQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Methyl-cinnamyl-sulfon 、 肉桂醛 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以75%的产率得到2'-methanesulfonyl[1,1';4',1'']terphenyl
  参考文献：
  名称：

  One-pot synthesis of functionalized p-terphenyl derivatives

  摘要：

  A one-pot synthetic route for preparing functionalized p-terphenyl derivatives 1 and 4 is developed. The route is easily carried from the treatment of cinnamyl aldehydes 2 with substituted allylsulfones 3 in good yields via the tandem intermolecular aldol condensation/intramolecular electrocyclization/oxidative dehydrogenation. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.023
• 作为产物：
  描述：

  肉桂醇 在 三乙胺 、 对甲苯磺酰氯 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 水 为溶剂， 反应 10.0h， 生成 Methyl-cinnamyl-sulfon
  参考文献：
  名称：

  One-pot synthesis of functionalized p-terphenyl derivatives

  摘要：

  A one-pot synthetic route for preparing functionalized p-terphenyl derivatives 1 and 4 is developed. The route is easily carried from the treatment of cinnamyl aldehydes 2 with substituted allylsulfones 3 in good yields via the tandem intermolecular aldol condensation/intramolecular electrocyclization/oxidative dehydrogenation. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.023

文献信息

• One-Pot Synthesis of Substituted Tetrahydrocyclobuta[<i>a</i>]naphthalenes by Domino Aldol Condensation/Olefin Migration/Electrocyclization
  作者：Meng-Yang Chang、Ming-Hao Wu、Yeh-Long Chen

  DOI：10.1021/ol401152w

  日期：2013.6.7

  A facile one-pot synthetic route for preparing the novel benzofused tricyclic skeleton of 1,2,2a,8b-tetrahydrocyclobuta[a]naphthalenes 5 is developed. The route was realized by a NaH-mediated tandem aldol condensation/olefin migration/electrocyclization of o-allylbenzaldehydes 1 with cinnamyl sulfones 3 in good yields.

  开发了一种容易的一锅合成路线，以制备新型的1,2,2a，8b-四氢环丁[ a ]萘5苯并稠合的三环骨架。该途径是通过NaH介导的串联羟醛缩合/烯烃迁移/邻烯丙基甲醛1与肉桂基砜3的电环化以高收率实现的。
• A New Reaction of Allylic Sulfones¹
  作者：Edward M. La Combe、Byron Stewart

  DOI：10.1021/ja01477a026

  日期：1961.8
• COMPOSITES COMPRISING NOVEL RTIL-BASED POLYMERS, AND METHODS OF MAKING AND USING SAME
  申请人：THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE

  公开号：US20150209776A1

  公开（公告）日：2015-07-30

  The invention includes compositions comprising curable imidazolium-functionalized poly(room-temperature ionic liquid) copolymers and homopolymers. The invention further includes methods of preparing and using the compositions of the invention. The invention further includes novel methods of preparing thin, supported, room-temperature ionic liquid-containing polymeric films on a porous support. In certain embodiments, the methods of the invention avoid the use of a gutter layer, which greatly reduces the overall gas permeance and selectivity of the composite membrane. In other embodiments, the films of the invention have increased gas selectivity and permeance over films prepared using methods described in the prior art.
• US9687840B2
  申请人：——

  公开号：US9687840B2

  公开（公告）日：2017-06-27
• [EN] COMPOSITES COMPRISING NOVEL RTIL-BASED POLYMERS, AND METHODS OF MAKING AND USING SAME<br/>[FR] COMPOSITES COMPRENANT DE NOUVEAUX POLYMÈRES À BASE DE LIQUIDES IONIQUES À TEMPÉRATURE AMBIANTE ET PROCÉDÉ DE FABRICATION ET D'UTILISATION ASSOCIÉS
  申请人：UNIV COLORADO REGENTS

  公开号：WO2014011661A2

  公开（公告）日：2014-01-16

  The invention includes compositions comprising curable imidazolium- functionalized poly(room-temperature ionic liquid) copolymers and homopolymers. The invention further includes methods of preparing and using the compositions of the invention. The invention further includes novel methods of preparing thin, supported, room-temperature ionic liquid-containing polymeric films on a porous support. In one embodiment, the methods of the invention avoid the use of a gutter layer, which greatly reduces the overall gas permeance and selectivity of the composite membrane. In another embodiment, the films of the invention have increased gas selectivity and permeance over films prepared using methods described in the prior art.